(l)-n-(benzyloxycarbonyl)pipecolic acid

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Names

[ Name ]:
(l)-n-(benzyloxycarbonyl)pipecolic acid

[Synonym ]:
(2S)-1-[(Benzyloxy)carbonyl]-2-piperidinecarboxylic acid
1,2-Piperidinedicarboxylic acid, 1-(phenylmethyl) ester
z-d-pip-oh
(S)-(-)-1-Cbz-2-piperidinecarboxylic acid
1-[(benzyloxy)carbonyl]piperidine-2-carboxylic acid
(S)-1-N-Cbz-Pipecolinic acid
MFCD01863645
1,2-Piperidinedicarboxylic acid, 1-(phenylmethyl) ester, (2S)-
1-[(Benzyloxy)carbonyl]-2-piperidinecarboxylic acid
(2S)-1-[(Benzyloxy)carbonyl]piperidine-2-carboxylic acid

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
443.9±45.0 °C at 760 mmHg

[ Melting Point ]:
111-115ºC(lit.)

[ Molecular Formula ]:
C₁₄H₁₇NO₄

[ Molecular Weight ]:
263.289

[ Flash Point ]:
222.3±28.7 °C

[ Exact Mass ]:
263.115753

[ PSA ]:
66.84000

[ LogP ]:
1.74

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.569

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

R-METHYL 1-CBZ-PIPERIDINE-2-CARBOXYLATE
(S)-1-CBZ-2-(HYDROXYMETHYL)PIPERIDINE
(S)-N-Cbz-piperidine-2-carbaldehyde
Isopropyl ether
Phenyl chloroformate
Pipecolic acid
N- CBZ-2-piperidinemethanol
Benzyl chloroformate
2-Piperidinemethanol
L(-)-Pipecolinic acid

DownStream

L(-)-Pipecolinic acid
Benzyl 2-carbamoylpiperidine-1-carboxylate
(S)-1-CBZ-2-(HYDROXYMETHYL)PIPERIDINE
L-1-Cbz-pipecolinamide

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

(d)-n-(benzyloxycarbonyl)pipecolic acid
L-N-benzyloxycarbonyl-[4-13C]glutamic acid 5-methyl ester
L-pipecolic acid chloride hydrochloride
(S)-tert-Butyl piperidine-2-carboxylate hydrochloride
Z-Ala-OPh
Benzyl 2-Formylpyrrolidine-1-carboxylate
(R)-6-methyl-N-(pyrrolidin-3-yl)pyridazine-3-sulfonamide hydrochloride
(S)-6-methyl-N-(pyrrolidin-3-yl)pyridazine-3-sulfonamide hydrochloride
(1-((6-Methylpyridazin-3-yl)sulfonyl)piperidin-4-yl)methanamine hydrochloride
(1-((6-Methylpyridazin-3-yl)sulfonyl)piperidin-3-yl)methanamine hydrochloride
1-((6-Methylpyridazin-3-yl)sulfonyl)piperidin-3-amine hydrochloride
(1-((6-Methylpyridazin-3-yl)sulfonyl)piperidin-2-yl)methanamine hydrochloride
1-((6-Methylpyridazin-3-yl)sulfonyl)piperazine-2-carboxylic acid hydrochloride
6-methyl-N-(piperidin-3-yl)pyridazine-3-sulfonamide hydrochloride
6-methyl-N-(piperidin-4-yl)pyridazine-3-sulfonamide hydrochloride
6-methyl-N-(piperidin-2-ylmethyl)pyridazine-3-sulfonamide hydrochloride

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