(l)-n-(benzyloxycarbonyl)pipecolic acid

Modify Date: 2025-08-25 14:56:25

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure
(l)-n-(benzyloxycarbonyl)pipecolic acid structure
 Common Name (l)-n-(benzyloxycarbonyl)pipecolic acid
CAS Number 28697-11-2 Molecular Weight 263.289
Density 1.3±0.1 g/cm3 Boiling Point 443.9±45.0 °C at 760 mmHg
Molecular Formula C14H17NO4 Melting Point 111-115ºC(lit.)
MSDS Chinese USA Flash Point 222.3±28.7 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name (2S)-1-phenylmethoxycarbonylpiperidine-2-carboxylic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 443.9±45.0 °C at 760 mmHg
Melting Point 111-115ºC(lit.)
Molecular Formula C14H17NO4
Molecular Weight 263.289
Flash Point 222.3±28.7 °C
Exact Mass 263.115753
PSA 66.84000
LogP 1.74
Vapour Pressure 0.0±1.1 mmHg at 25°C
Index of Refraction 1.569

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2933399090

 Synthetic Route

R-METHYL 1-CBZ-PIPERIDINE-2-CARBOXYLATE structure

R-METHYL 1-CBZ-...

CAS#:60369-19-9

~99%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Golec, Julian M.C. Patent: US2002/61853 A1, 2002 ;
(S)-1-CBZ-2-(HYDROXYMETHYL)PIPERIDINE structure

(S)-1-CBZ-2-(HY...

CAS#:212557-00-1

~74%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Sanchez-Sancho, Francisco; Herradon, Bernardo Tetrahedron Asymmetry, 1998 , vol. 9, # 11 p. 1951 - 1965
(S)-N-Cbz-piperidine-2-carbaldehyde structure

(S)-N-Cbz-piper...

CAS#:212556-95-1

~73%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Sanchez-Sancho, Francisco; Herradon, Bernardo Tetrahedron Asymmetry, 1998 , vol. 9, # 11 p. 1951 - 1965
Isopropyl ether structure

Isopropyl ether

CAS#:108-20-3

Phenyl chloroformate structure

Phenyl chloroformate

CAS#:1885-14-9

Pipecolic acid structure

Pipecolic acid

CAS#:4043-87-2

~%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Dr. Lo Zambeletti S.p.A. Patent: US4826819 A1, 1989 ;
N- CBZ-2-piperidinemethanol structure

N- CBZ-2-piperi...

CAS#:105706-75-0

~%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Sanchez-Sancho, Francisco; Herradon, Bernardo Tetrahedron Asymmetry, 1998 , vol. 9, # 11 p. 1951 - 1965
Benzyl chloroformate structure

Benzyl chloroformate

CAS#:501-53-1

~%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Sanchez-Sancho, Francisco; Herradon, Bernardo Tetrahedron Asymmetry, 1998 , vol. 9, # 11 p. 1951 - 1965
2-Piperidinemethanol structure

2-Piperidinemethanol

CAS#:3433-37-2

~%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Sanchez-Sancho, Francisco; Herradon, Bernardo Tetrahedron Asymmetry, 1998 , vol. 9, # 11 p. 1951 - 1965
Benzyl chloroformate structure

Benzyl chloroformate

CAS#:501-53-1

L(-)-Pipecolinic acid structure

L(-)-Pipecolini...

CAS#:3105-95-1

~%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Gurjar; Ghosh, Lakshmi; Syamala; Jayasree Tetrahedron Letters, 1994 , vol. 35, # 47 p. 8871 - 8872
N-Cbz-2-Piperidinecarboxylic acid structure

N-Cbz-2-Piperid...

CAS#:28697-07-6

~%

(l)-n-(benzyloxycarbonyl)pipecolic acid Structure

(l)-n-(benzylox...

CAS#:28697-11-2

Literature: Coppola, Gary M.; Damon, Robert E.; Eskesen, J. Bruce; France, Dennis S.; Paterniti Jr., James R. Bioorganic and Medicinal Chemistry Letters, 2005 , vol. 15, # 3 p. 809 - 812

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

(2S)-1-[(Benzyloxy)carbonyl]-2-piperidinecarboxylic acid
1,2-Piperidinedicarboxylic acid, 1-(phenylmethyl) ester
z-d-pip-oh
(S)-(-)-1-Cbz-2-piperidinecarboxylic acid
1-[(benzyloxy)carbonyl]piperidine-2-carboxylic acid
(S)-1-N-Cbz-Pipecolinic acid
MFCD01863645
1,2-Piperidinedicarboxylic acid, 1-(phenylmethyl) ester, (2S)-
1-[(Benzyloxy)carbonyl]-2-piperidinecarboxylic acid
(2S)-1-[(Benzyloxy)carbonyl]piperidine-2-carboxylic acid
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