Aminooxyacetic acid hemihydrochloride

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Names

[ Name ]:
Aminooxyacetic acid hemihydrochloride

[Synonym ]:
O-Carboxymethylhydroxylamine hemihydrochloride
(Aminooxy)acetic acid hydrochloride (2:1)
2-aminooxyacetic acid
(carboxymethoxy)amine hemihydrochloride
Acetic acid, 2-(aminooxy)-, hydrochloride (2:1)
Carboxymethoxylamine-D2
Aminyloxy-acetic Acid Hemihydrochlorid
2-AMINOOXY-ACETICACIHYDROCHLORIDE
aminooxyaceticacidhemichloride
AMinooxyacetic acid Hydrochloride
O-(carboxymethyl) hydroxylamine hemichloride
2-aminooxy-aceticacihydrochloride(2:1)
Bis((aminooxy)acetic) acid hydrochloride
MFCD00012955
Aminooxyacetic acid hemihydrochloride
2-(Aminooxy)acetic acid hydrochloride(2:1)
(Aminooxy)acetic Acid Hemihydrochloride
(aminooxy)-aceticacihydrochloride(2:1)
CarboxyMethoxylaMine HeMihydrochloride
O-(Carboxymethyl)hydroxylamine hemihydrochloride
Carboxymethoxyamine hemihydrochloride
EINECS 220-862-3
(carbomethoxy)amine hemihydrochloride

Chemical & Physical Properties

[ Boiling Point ]:
326.7ºC at 760 mmHg

[ Melting Point ]:
156 °C (dec.)(lit.)

[ Molecular Formula ]:
NH₂OCH₂COOH·_0.5HCl

[ Molecular Weight ]:
109.30

[ Flash Point ]:
151.4ºC

[ PSA ]:
145.10000

[ LogP ]:
0.12520

[ Vapour Pressure ]:
4.24E-05mmHg at 25°C

[ Storage condition ]:
-20°C Freezer

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AF3150000

CAS REGISTRY NUMBER :: 2921-14-4

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C4-H10-N2-O6.Cl-H

MOLECULAR WEIGHT :: 218.62

WISWESSER LINE NOTATION :: ZO1VQ 2 &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 65 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JMPCAS Journal of Medicinal and Pharmaceutical Chemistry. (Washington, DC) V.1-5, 1959-62. For publisher information, see JMCMAR. Volume(issue)/page/year: 5,464,1962

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 91 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Skin and Appendages - hair

REFERENCE :: NEPHBW Neuropharmacology. (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, UK) V.9- 1970- Volume(issue)/page/year: 21,803,1982

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 1193 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
AF3150000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

β-Estradiol-6-one 6-(O-carboxymethyloxime)
(Boc-aminooxy)acetic Acid
6-Oxoestriol (carboxymethyl)oxime
Fmoc-aoac-oh
[[(α-Methylbenzylidene)amino]oxy]acetic acid
2-[bis(2-chloroethyl)aminooxy]acetic acid
2-[(E)-1-(4-ethyl-3-oxo-1,4-benzoxazin-6-yl)ethylideneamino]oxyacetic acid
ethyl 2-(aminooxy)acetate
2-[(6-oxocyclohexa-2,4-dien-1-ylidene)methylamino]oxyacetic acid
Acetic acid, (aminooxy)-, ethyl ester, hydrochloride

Articles

Synthesis and in vitro antibacterial properties of 2-(3-bromo-5-isoxazolylideneamino-oxy)acetamido-beta-lactam derivatives.

Il Farmaco 46 , 887, (1991)

The synthesis of new 2-(3-bromo-5-isoxazolylideneamino-oxy)acetic acids and their condensation derivatives with suitable beta-lactam nuclei is reported. Their antibacterial properties have been tested...

Tetrahedron Lett. 34 , 4347, (1993)

Aminooxyacetic Acid, Hydrochloride SaltDiscontinued See: C178730
Aminooxy-acetic acid butyl ester; hydrochloride
(Boc-aminooxy)acetic Acid
2-[bis(2-chloroethyl)aminooxy]acetic acid
ethyl 2-(aminooxy)acetate
cis-N,N'-Bis(ethoxycarbonylmethoxy)-1,2-cyclohexanediamine