P-TOLYL TRIFLATE

Suppliers

Names

[ Name ]:
P-TOLYL TRIFLATE

[Synonym ]:
para-tolyl triflate
4-methylphenyl triflate
p-Tolyl trifluoromethanesulfonate
4-tolyltriflate
p-trifluoromethanesulfonyloxytoluene
MFCD00192507
4-Tolyl trifluoromethanesulfonate
p-Tolyl Triflate
ghl.PD_Mitscher_leg0.1333
trifluoromethanesulfonic acid p-tolyl ester
4-Methylphenyl trifluoromethanesulfonate

Chemical & Physical Properties

[ Density]:
1.342 g/mL at 25ºC(lit.)

[ Boiling Point ]:
115ºC50 mm Hg(lit.)

[ Molecular Formula ]:
C₈H₇F₃O₃S

[ Molecular Weight ]:
240.20000

[ Flash Point ]:
192 °F

[ Exact Mass ]:
240.00700

[ PSA ]:
51.75000

[ LogP ]:
3.30420

[ Vapour Pressure ]:
0.0242mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.441(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314-H331-H351

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
23/24/25-34-40

[ Safety Phrases ]:
16-26-36/37/39-45

[ RIDADR ]:
UN 3265 8/PG 2

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

p-Cresol
triflic anhydride
(p-toluene)diazonium trifluoromethanesulfonate
Trifluoromethanesulfonic acid
4-methylbenzenediazonium tetrafluoroborate
Imidazole
1H-Imidazole,1-[(trifluoromethyl)sulfonyl]-
1-Triazene,3,3-dimethyl-1-(4-methylphenyl)-
(4-methylphenyl)-piperidin-1-yldiazene

DownStream

2-(4-methylphenyl)-1-phenylpropan-1-one
4-Fluorotoluene
3-Fluorotoluene
4'-Methyl-4-biphenylcarbonitrile
4-Phenyltoluene
3-(Trifluoromethyl)-1H-pyrazole-5-carboxamide
1-(4'-Methyl-4-biphenylyl)ethanone
4-METHYL-2?-NITROBIPHENYL
nitrobenzene
4-Methylbenzeneboronic acid neopentyl glycol ester

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

J. Am. Chem. Soc. 130(1) , 195-200, (2008)

The asymmetric alpha-arylation of ketones with aryl triflates is described, and the use of this electrophile with nickel and palladium catalysts containing a segphos derivative increases substantially...

Direct arylation of azine N-oxides with aryl triflates. Schipper DJ, et al.

Tetrahedron 65(26) , 4977-4983, (2009)

p-tolyl triflate
p-tolyl diethyldithiocarbamate
p-Tolyl selenocyanate
p-tolyl N-phenylethanimidothioate
p-tolyl-2,3,4-tri-O-benzyl-6-O-trityl-1-thio-β-D-glucopyranoside
p-tolyl N,3-diphenylprop-2-enimidothioate
N-[1-(2-hydroxy-2-methylpropyl)azetidin-3-yl]prop-2-enamide
N-Cyclopropyl-N-((1-ethyl-3-methyl-1H-pyrazol-4-yl)methyl)acrylamide
N-[4-(3-Phenyl-1H-1,2,4-triazol-5-yl)cyclohexyl]prop-2-enamide
N-(2-{3-hydroxy-8-azabicyclo[3.2.1]octan-8-yl}ethyl)prop-2-enamide
N-[2,2,2-Trifluoro-1-(1H-pyrrol-2-yl)ethyl]prop-2-enamide
N-(2-{6-fluoro-1H-pyrrolo[2,3-b]pyridin-3-yl}ethyl)prop-2-enamide
N-[carbamoyl(3-fluorophenyl)methyl]-N-methylprop-2-enamide
N-[1-(4-Cyclopropyl-6-oxo-1H-pyrimidin-2-yl)cyclohexyl]prop-2-enamide
N-[2,2-difluoro-2-(4,5,6,7-tetrahydro-2H-indazol-3-yl)ethyl]prop-2-enamide
N-[(1-Methyl-3-pyridin-2-ylpyrazol-4-yl)methyl]prop-2-enamide

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