Phenazine methylsulfate

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Names

[ CAS No. ]:
299-11-6

[ Name ]:
Phenazine methylsulfate

[Synonym ]:
EINECS 206-072-1
5-methylphenylazinium methyl sulfate
PHENAZINE METHOLSULPHATE
Phenazine Methyl Sulfate
N-methyl phenazinium methylsulphate
Phenazine Methoshlphate
PMS,phenazine methosulfate
Phenazinium, 5-methyl-, methyl sulfate
5-methylphenazinium methylsulfate
5-Methylphenazinium methosulfate
PHENAZINE METHOSULFATE
5-Methylphenazin-5-ium methyl sulfate
PMS
MFCD00011923
PhenazineMethosulphate~
Phenazine methosulfa
5-Methyl-phenazinium
N-methylphenazinium methyl sulfate

Chemical & Physical Properties

[ Melting Point ]:
158-160 °C (dec.)(lit.)

[ Molecular Formula ]:
C14H14N2O4S

[ Molecular Weight ]:
306.337

[ Exact Mass ]:
306.067413

[ PSA ]:
91.58000

[ LogP ]:
2.38630

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
soluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SG1645000
CHEMICAL NAME :
Phenazinium, 5-methyl-, methylsulfate
CAS REGISTRY NUMBER :
299-11-6
LAST UPDATED :
199701
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C13-H11-N2.C-H3-O4-S
MOLECULAR WEIGHT :
306.36
WISWESSER LINE NOTATION :
T C666 BK INJ B1 &WSO&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
19 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA adduct
TEST SYSTEM :
Fish - salmon Sperm
DOSE/DURATION :
3300 nmol/L
REFERENCE :
BICHAW Biochemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1962- Volume(issue)/page/year: 8,1238,1969 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3658 No. of Facilities: 194 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 2761 (estimated) No. of Female Employees: 2298 (estimated)

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R36/37/38;R68

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ RTECS ]:
SG1645000

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Phenazine
  • Dimethyl sulfate
  • 5,10-dihydro-5-methylphenazine
  • 5,10-Dimethyldihydrophenazine
  • 5,10-dibenzylphenazine
  • 5-benzyl-10-methylphenazine
  • 2-Nitrodiphenylamine
  • 5,10-dihydrophenazine

DownStream

  • Pyocyanine
  • Hemipyocyanine
  • 5,10-dihydro-5-methylphenazine

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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Related Compounds

  • Phenazine, 1,2,3,4,4a,5,10,10a-octahydro- (7CI,9CI)
  • Phenazine, 1-(methylamino)- (7CI)
  • phenazine-1-carbaldehyde
  • phenazine-1-carbonitrile
  • Phenazine, 5,10-dioxide
  • Phenazine, 1,2-diamino- (7CI,8CI)
  • 3-(1,3-benzodioxol-5-yl)-5-[1-(2,5-dimethoxyphenyl)-5-methyl-1H-1,2,3-triazol-4-yl]-1,2,4-oxadiazole
  • N-[2-(3,4-Dimethoxyphenyl)ethyl]-2-[5-methyl-2-(1-methylethyl)phenoxy]acetamide
  • (E)-2-cyano-N-(4-ethoxyphenyl)-3-(2-methoxyphenyl)prop-2-enamide
  • 4H-pyrazol-3-amine
  • 1-(4-bromophenyl)-3-[1-(3-isopropenylphenyl)-1-methyl-ethyl]urea
  • N-[4-(Acetylmethylamino)phenyl]-2-methylpropanamide
  • 1-[(2-Chlorophenyl)methoxy]-4-isopropylbenzene
  • 8,9,10-Trimethoxy-6-oxo-6H-dibenzo[b,d]pyran-3-yl 2-([1,1a(2)-biphenyl]-4-yloxy)acetate
  • 8,9,10-Trimethoxy-6-oxo-6H-dibenzo[b,d]pyran-3-yl 2-(4-chloro-2-methylphenoxy)acetate
  • Methyl 5-bromo-2-(2-phenylacetamido)benzoate
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