Vanadyl acetylacetonate

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Names

[ CAS No. ]:
3153-26-2

[ Name ]:
Vanadyl acetylacetonate

[Synonym ]:
Bis[(3Z)-4-(hydroxy-κO)-3-penten-2-onato](oxo)vanadium
Acetylacetone Vanadium(IV)oxy Salt
VANADYL PENTANEDIONATE
VANANDEYLACETYLACETONATE
VANADYL ACETYLACETONE
vanadium(IV)oxyacetylacetonate
Vanadyl acetylaceton
EINECS 221-590-8
Vanadyl Acetylacetonate
Vanadium oxyacetoacetonate
oxobis(2,4-pentanedionato)vanadium(IV)
Bis[(3Z)-4-(hydroxy-κO)pent-3-en-2-onato](oxo)vanadium
VO(acac)2 (Vanadium(IV)-oxy acetylacetonate
VANADIUMOXY ACETYLACETONATE
Vanadium, bis[(3Z)-4-(hydroxy-κO)-3-penten-2-onato]oxo-
VO(acac)2
bis(acetylacetonate)oxovanadium
Vanadyl(IV) acetylacetonate
Vanadium(IV)-oxy acetylacetonate
vanadium di(acetylacetonate)
V(IV)-oxyacetylacetonate
Vanadylacetylacetonate
Bis(2,4-pentanedionato)vanadium(IV) Oxide
Vanadium(IV)oxy Acetylacetonate
VANADYL 2,4-PENTANEDIONATE
MFCD00000032
bis(acetylacetonato)oxovanadium
Vanadium(IV)oxy Acetyla

Chemical & Physical Properties

[ Density]:
1,4 g/cm3

[ Boiling Point ]:
140°C 13mm

[ Melting Point ]:
235 °C (dec.)(lit.)

[ Molecular Formula ]:
C10H14O5V

[ Molecular Weight ]:
265.157

[ Flash Point ]:
79 °C

[ Exact Mass ]:
265.028076

[ PSA ]:
69.67000

[ LogP ]:
1.80140

[ Stability ]:
Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
practically insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
22-26-36-36/37/39

[ RIDADR ]:
3285

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29420000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • VANADIUM(IV) OXIDE SULFATE
  • 2,4-Pentandione
  • Vanadium
  • 2,4-Pentanedione-vanadium (3:1)

DownStream

  • tert-Butyl acetate
  • tert-Butyl peroxyacetate
  • Di-tert-butyl peroxide
  • acetic acid
  • Pyruvic acid
  • tert-Butanol
  • Acetone
  • 2,4-Pentandione
  • Brenztraubensaeure-methylester-(2,4-dinitro-phenylhydrazon)
  • 2,4-Pentanedione-vanadium (3:1)

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Design, synthesis and characterization of novel binary V(V)-Schiff base materials linked with insulin-mimetic vanadium-induced differentiation of 3T3-L1 fibroblasts to adipocytes. Structure-function correlations at the molecular level.

J. Inorg. Biochem. 147 , 99-115, (2015)

Among the various roles of vanadium in the regulation of intracellular signaling, energy metabolism and insulin mimesis, its exogenous activity stands as a contemporary challenge currently under inves...

[Oxidation of phenothiazine and its N-methyl derivative by the combination of iodobenzene and vanadium acetylacetonate].

Pharmazie 40(3) , 202-3, (1985)

X-ray fluorescence microscopy demonstrates preferential accumulation of a vanadium-based magnetic resonance imaging contrast agent in murine colonic tumors.

Mol. Imaging 14 , (2015)

Contrast agents that specifically enhance cancers on magnetic resonance imaging (MRI) will allow earlier detection. Vanadium-based chelates (VCs) selectively enhance rodent cancers on MRI, suggesting ...


More Articles

Related Compounds

  • VANADYL 5 14 23 32-TETRAPHENYL-2 3-
  • vanadyl sulphate VOSO4, β
  • vanadyl sulfate hydrate
  • vanadyl (V) chloride azide
  • VANADYL 3,10,17,24-TETRA-TERT-BUTYL-1,8,15,22-TETRAKIS(DIMETHYLAMINO)-29H-PHTHALOCYANINE
  • VANADYL 2,3-NAPHTHALOCYANIDE
  • Chromium, triaqua[3-[[4,5-dihydro-3-methyl-5-(oxo-I masculineO)-1-phenyl-1H-pyrazol-4-yl]azo-I masculineN1]-4-(hydroxy-I masculineO)-5-nitrobenzenesulfonato(3-)]-, (OC-6-24)-
  • Chromium, triaqua[4-[[4,5-dihydro-3-methyl-5-(oxo-I masculineO)-1-phenyl-1H-pyrazol-4-yl]azo-I masculineN1]-3-(hydroxy-I masculineO)-1-naphthalenesulfonato(3-)]-, (OC-6-24)-
  • 4-[[(1R)-3-(Dimethylamino)-3-oxo-1-[(phenylthio)methyl]propyl]amino]-8-(trifluoromethyl)-3-quinolinecarboxylic acid (2E)-2-nonylidenehydrazide
  • Boron, [[2,2a(2)-(imino-I masculineN)bis[ethanolato-I masculineO]](2-)][(1S)-4-methoxy-1-[[N-[(phenylmethoxy)carbonyl]-L-phenylalanyl-D-prolyl]amino]butyl]-, (T-4)-
  • Bis[3-[4,5-dihydro-4-[2-[2-(hydroxy-I masculineO)-4-nitrophenyl]diazenyl-I masculineN2]-3-methyl-5-(oxo-I masculineO)-1H-pyrazol-1-yl]benzenesulfonamidato(2-)]chromate(1-)
  • (I+/-Z)-2-Amino-I+/--(methoxyimino)-N-[(5aR,6R)-1,4,5a,6-tetrahydro-1,7-dioxo-3H,7H-azeto[2,1-b]furo[3,4-d][1,3]thiazin-6-yl]-5-thiazoleacetamide
  • (SP-4-1)-[[4,4a(2),4a(2)a(2),4a(2)a(2)a(2)-(21H,23H-Porphine-5,10,15,20-tetrayl-I masculineN21,I masculineN22,I masculineN23,I masculineN24)tetrakis[2,6-bis(1,1-dimethylethyl)phenolato]](2-)]nickel
  • 1,3,5-Triazine-1(2H)-acetic acid, 3-[(2-chloro-5-thiazolyl)methyl]tetrahydro-I+/--[2-(methylthio)ethyl]-4-(nitroimino)-, ethyl ester, (I+/-S,4E)-
  • 1,3,5-Triazine-1(2H)-acetic acid, 3-[(6-chloro-3-pyridinyl)methyl]tetrahydro-I+/--[(1S)-1-methylpropyl]-4-(nitroimino)-, ethyl ester, (I+/-S,4E)-
  • Methyl (1R,2S,5S)-3-[(2S)-2-cyclohexyl-2-[[(1,1-dimethylethoxy)carbonyl]amino]acetyl]-6,6-dimethyl-3-azabicyclo[3.1.0]hexane-2-carboxylate
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