Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)

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Names

[ CAS No. ]:
31930-36-6

[ Name ]:
Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)

[Synonym ]:
MFCD00209584
Ethyl cis-3-Iodoacrylate
ethyl cis-3-iodo-acrylate
cis-3-iodo-acrylic acid ethyl ester
cis-3-Iodoacrylic Acid Ethyl Ester

Chemical & Physical Properties

[ Density]:
1.765 g/mL at 25ºC(lit.)

[ Boiling Point ]:
85ºC20 mm Hg(lit.)

[ Molecular Formula ]:
C5H7IO2

[ Molecular Weight ]:
226.01200

[ Flash Point ]:
210 °F

[ Exact Mass ]:
225.94900

[ PSA ]:
26.30000

[ LogP ]:
1.49820

[ Index of Refraction ]:
n20/D 1.533(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2916190090

Synthetic Route

Precursor & DownStream

Precursor

  • Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)
  • Ethyl propiolate
  • Ethanol
  • (E)-3-IODO-2-PROPENOIC ACID
  • (E/Z)-3-iodoacrylic acid

DownStream

  • Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)
  • N-Phenylmaleimide
  • 1-iodohept-1-en-3-ol
  • 3-iodoprop-2-enal
  • ethyl 7-thiophen-2-ylhepta-2,4,6-trienoate
  • Ethyl 3-(trimethylsilyl)-2-propynoate
  • N-Cyclohexylmaleimide
  • 5-phenyl-3H-furan-2-one
  • ethyl 3-phenylsulfanylprop-2-enoate
  • ethyl 6-hydroxy-4-methylhexa-2,4-dienoate

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

A simple and convenient method for the preparation of (Z)-β-iodoacrolein and of (Z)- or (E)-γ-iodo allylic alcohols: (Z)- and (E)-1-iodohept-1-en-3-ol. Marek I, et al.

Organic Synth. 74 , 194, (1997)

Regiochemical control in the metal-catalyzed transposition of allylic silyl ethers. Hansen EC and Lee D.

J. Am. Chem. Soc. 128(25) , 8142-8143, (2006)

Stereo-and regiospecific Cu-catalyzed cross-coupling reaction of vinyl iodides and thiols: a very mild and general route for the synthesis of vinyl sulfides. Kabir MS, et al.

Org. Lett. 10(15) , 3363-3366, (2008)


More Articles


Related Compounds

  • 5-[(Z)-1-(3,4-dimethoxyphenyl)methylidene]-2-(4-hydroxyanilino)-1,3-thiazol-4-one
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 1-(Pyrimidin-5-yl)propan-1-imine
  • tert-Butyl-DL-alanine