Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)
Suppliers
Names
[ CAS No. ]:
31930-36-6
[ Name ]:
Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)
[Synonym ]:
MFCD00209584
Ethyl cis-3-Iodoacrylate
ethyl cis-3-iodo-acrylate
cis-3-iodo-acrylic acid ethyl ester
cis-3-Iodoacrylic Acid Ethyl Ester
Chemical & Physical Properties
[ Density]:
1.765 g/mL at 25ºC(lit.)
[ Boiling Point ]:
85ºC20 mm Hg(lit.)
[ Molecular Formula ]:
C5H7IO2
[ Molecular Weight ]:
226.01200
[ Flash Point ]:
210 °F
[ Exact Mass ]:
225.94900
[ PSA ]:
26.30000
[ LogP ]:
1.49820
[ Index of Refraction ]:
n20/D 1.533(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
26
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
2916190090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2916190090
[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%
Articles
Organic Synth. 74 , 194, (1997)
Regiochemical control in the metal-catalyzed transposition of allylic silyl ethers. Hansen EC and Lee D.
J. Am. Chem. Soc. 128(25) , 8142-8143, (2006)
Stereo-and regiospecific Cu-catalyzed cross-coupling reaction of vinyl iodides and thiols: a very mild and general route for the synthesis of vinyl sulfides. Kabir MS, et al.
Org. Lett. 10(15) , 3363-3366, (2008)