Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)

Modify Date: 2024-01-09 18:42:15

Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) Structure
Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) structure
Common Name Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)
CAS Number 31930-36-6 Molecular Weight 226.01200
Density 1.765 g/mL at 25ºC(lit.) Boiling Point 85ºC20 mm Hg(lit.)
Molecular Formula C5H7IO2 Melting Point N/A
MSDS Chinese USA Flash Point 210 °F
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name cis-3-iodoacrylic acid ethyl ester
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.765 g/mL at 25ºC(lit.)
Boiling Point 85ºC20 mm Hg(lit.)
Molecular Formula C5H7IO2
Molecular Weight 226.01200
Flash Point 210 °F
Exact Mass 225.94900
PSA 26.30000
LogP 1.49820
Index of Refraction n20/D 1.533(lit.)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26
RIDADR NONH for all modes of transport
HS Code 2916190090

 Synthetic Route

Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) Structure

Ethyl cis-3-Iod...

CAS#:31930-36-6

~86%

Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) Structure

Ethyl cis-3-Iod...

CAS#:31930-36-6

Literature: Zhang, Wen; Xu, Huadong; Xu, Hui; Tang, Weiping Journal of the American Chemical Society, 2009 , vol. 131, p. 3832 - 3833

~79%

Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) Structure

Ethyl cis-3-Iod...

CAS#:31930-36-6

Literature: Ghomsi, Joseph-Nathan Tene; Goureau, Olivine; Treilhou, Michel Tetrahedron Letters, 2005 , vol. 46, # 9 p. 1537 - 1539

~90%

Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) Structure

Ethyl cis-3-Iod...

CAS#:31930-36-6

Literature: Takeuchi, Ryo; Tanabe, Keisuke; Tanaka, Shigeru Journal of Organic Chemistry, 2000 , vol. 65, # 5 p. 1558 - 1561

~%

Ethyl cis-3-Iodoacrylate (stabilized with Copper chip) Structure

Ethyl cis-3-Iod...

CAS#:31930-36-6

Literature: Tamba, Shunsuke; Fujii, Ryosuke; Mori, Atsunori; Hara, Kohjiro; Koumura, Nagatoshi Chemistry Letters, 2011 , vol. 40, # 9 p. 978 - 979

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles4

More Articles
A simple and convenient method for the preparation of (Z)-β-iodoacrolein and of (Z)- or (E)-γ-iodo allylic alcohols: (Z)- and (E)-1-iodohept-1-en-3-ol. Marek I, et al.

Organic Synth. 74 , 194, (1997)

Regiochemical control in the metal-catalyzed transposition of allylic silyl ethers. Hansen EC and Lee D.

J. Am. Chem. Soc. 128(25) , 8142-8143, (2006)

Stereo-and regiospecific Cu-catalyzed cross-coupling reaction of vinyl iodides and thiols: a very mild and general route for the synthesis of vinyl sulfides. Kabir MS, et al.

Org. Lett. 10(15) , 3363-3366, (2008)

 Synonyms

MFCD00209584
Ethyl cis-3-Iodoacrylate
ethyl cis-3-iodo-acrylate
cis-3-iodo-acrylic acid ethyl ester
cis-3-Iodoacrylic Acid Ethyl Ester