Diethyl diallylmalonate
Suppliers
Names
[ CAS No. ]:
3195-24-2
[ Name ]:
Diethyl diallylmalonate
[Synonym ]:
Diethyl diallylmalonate
diethyl 2,2-diprop-2-enylpropane-1,3-dioate
Malonic acid, diallyl-, diethyl ester
Diallylmalonic Acid Diethyl Ester
EINECS 221-696-4
diethyl 2,2-diallylmalonate
Propanedioic acid, 2,2-di-2-propen-1-yl-, diethyl ester
Propanedioic acid, di-2-propenyl-, diethyl ester
MFCD00009126
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
243.5±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C13H20O4
[ Molecular Weight ]:
240.296
[ Flash Point ]:
106.7±24.4 °C
[ Exact Mass ]:
240.136154
[ PSA ]:
52.60000
[ LogP ]:
3.41
[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.455
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2917190090
Synthetic Route
Customs
[ HS Code ]: 2917190090
[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Chemistry 19(3) , 1002-12, (2013)
An efficient procedure is described for ring-closing metathesis reactions. A conversion of 95% for diethyl diallylmalonate in dilute solution could be achieved within a few minutes, reaching TOF = 417...
Chem. Commun. (Camb.) (11) , 1456-8, (2005)
Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate...