Diethyl diallylmalonate

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Names

[ CAS No. ]:
3195-24-2

[ Name ]:
Diethyl diallylmalonate

[Synonym ]:
Diethyl diallylmalonate
diethyl 2,2-diprop-2-enylpropane-1,3-dioate
Malonic acid, diallyl-, diethyl ester
Diallylmalonic Acid Diethyl Ester
EINECS 221-696-4
diethyl 2,2-diallylmalonate
Propanedioic acid, 2,2-di-2-propen-1-yl-, diethyl ester
Propanedioic acid, di-2-propenyl-, diethyl ester
MFCD00009126

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
243.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C13H20O4

[ Molecular Weight ]:
240.296

[ Flash Point ]:
106.7±24.4 °C

[ Exact Mass ]:
240.136154

[ PSA ]:
52.60000

[ LogP ]:
3.41

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.455

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Synthetic Route

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Low catalyst loading in ring-closing metathesis reactions.

Chemistry 19(3) , 1002-12, (2013)

An efficient procedure is described for ring-closing metathesis reactions. A conversion of 95% for diethyl diallylmalonate in dilute solution could be achieved within a few minutes, reaching TOF = 417...

Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate.

Chem. Commun. (Camb.) (11) , 1456-8, (2005)

Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate...


More Articles


Related Compounds

  • diethyl diallylmalonate
  • diethyl (4-methoxyphenylthio)methylphosphonate
  • diethyl N-methylaminomethylphosphonate
  • diethyl 2-(1-ethylsulfanyl-2-methylpropyl)propanedioate
  • diethyl 1-cyano-1-(4-isobutylphenyl)ethylphosphate
  • diethyl 2-benzyl-2-pentylpropanedioate
  • Methyl 1-[1-hydroxy-4-(propan-2-yl)cyclohexyl]cyclopropane-1-carboxylate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 5-Chloro-7-cyclopentyl-2-propyl-[1,2,4]triazolo[1,5-a]pyridine
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 5-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-methylpentanamido]pentanoic acid
  • tert-butyl N-[2-(2-bromopropyl)-5-chlorophenyl]carbamate
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide