Diethyl diallylmalonate

Diethyl diallylmalonate Structure
Diethyl diallylmalonate structure
Common Name Diethyl diallylmalonate
CAS Number 3195-24-2 Molecular Weight 240.296
Density 1.0±0.1 g/cm3 Boiling Point 243.5±0.0 °C at 760 mmHg
Molecular Formula C13H20O4 Melting Point N/A
MSDS Chinese USA Flash Point 106.7±24.4 °C
Symbol GHS07
GHS07
Signal Word Warning

Low catalyst loading in ring-closing metathesis reactions.

Chemistry 19(3) , 1002-12, (2013)

An efficient procedure is described for ring-closing metathesis reactions. A conversion of 95% for diethyl diallylmalonate in dilute solution could be achieved within a few minutes, reaching TOF = 4173 min(-1), with very low loading of commercially available ...

Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate.

Chem. Commun. (Camb.) (11) , 1456-8, (2005)

Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.