Bis(dibenzylideneacetone)palladium

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Names

[ CAS No. ]:
32005-36-0

[ Name ]:
Bis(dibenzylideneacetone)palladium

[Synonym ]:
(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one
1,4-Pentadien-3-one, 1,5-diphenyl-, (1E,4E)-, palladium salt (2:1)
Bis(dibenzylideneacetone) palladium(0)
(1E,4E)-1,5-Diphenyl-1,4-pentadien-3-one - palladium (2:1)
Bis(dibenzylideneacetone)palladium(0)
bis-(dibenzylideneacetone)palladium(0)
Palladium(0) bis(dibenzylideneacetone)
(1E,4E)-1,5-Diphenylpenta-1,4-dien-3-one - palladium (2:1)
PD(DBA)2
palladium bis(dibenzylideneacetone)
Bis(dibenzylideneacetone)palladium
MFCD00051942

Chemical & Physical Properties

[ Boiling Point ]:
400.7ºC at 760 mmHg

[ Melting Point ]:
150°C

[ Molecular Formula ]:
C36H42O2Pd

[ Molecular Weight ]:
613.14

[ Flash Point ]:
176.1ºC

[ Exact Mass ]:
574.112427

[ PSA ]:
34.14000

[ LogP ]:
7.96460

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S22-S24/25-S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914399090

Precursor & DownStream

Precursor

DownStream

  • Bis(tricyclohexylphosphine)palladium(0)
  • 1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene
  • Tetrakis(triphenylphosphine)palladium
  • BIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(0)
  • palladium,triphenylphosphane
  • 1-N,1-N,6-N,6-N-tetraphenylpyrene-1,6-diamine
  • palladium,tritert-butyl-(2,4-dimethylphenyl)iodanuidylphosphanium
  • 1,5-Diphenyl-3-pentanone
  • Pyrido[2,3-b]pyrazine, 7-methyl- (9CI)

Customs

[ HS Code ]: 2914399090

[ Summary ]:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Palladium-catalyzed, asymmetric Mizoroki-Heck reaction of benzylic electrophiles using phosphoramidites as chiral ligands.

J. Am. Chem. Soc. 134(29) , 11833-5, (2012)

We report herein the first examples of asymmetric Mizoroki-Heck reactions using benzyl electrophiles. A new phosphoramidite was identified to be an effective chiral ligand in the palladium-catalyzed r...

Controlling olefin isomerization in the heck reaction with neopentyl phosphine ligands.

J. Org. Chem. , (2014)

The use of neopentyl phosphine ligands was examined in the coupling of aryl bromides with alkenes. Di-tert-butylneopentylphosphine (DTBNpP) was found to promote Heck couplings with aryl bromides at am...

Sterically bulky thioureas as air- and moisture-stable ligands for pd-catalyzed Heck reactions of aryl halides.

Org. Lett. 6 , 1577, (2004)

We demonstrate that sterically bulky N,N'-disubstituted cyclic thiourea-Pd(0) complexes are air- and moisture-stable and highly active catalysts for palladium-catalyzed Heck reaction of aryl iodides a...


More Articles

Related Compounds

  • Tris(dibenzylideneacetone)dipalladium(0)
  • White catalyst
  • Bis(triphenylphosphine) Palladium (II) Chloride
  • bis(diphenylphosphino)palladium(II) chloride
  • bis(dimethylphenylphosphine) palladium(II) chloride
  • Bis(acetonitrile)palladium(II) p-toluenesulfonate
  • 3-(2-Isocyanatopropan-2-yl)thiolane
  • tert-Butyl (2-chloro-4-(difluoromethyl)thiophen-3-yl)carbamate
  • 4-Amino-1-(3-hydroxyphenyl)cyclohexane-1-carboxylic acid
  • 6-(Dimethylamino)-5-(2-methylpropoxy)-2-pyrazinecarboxylic acid
  • 1-(1-Ethynylcyclopropyl)-2-methylcyclopropane
  • 2-Methyl-2-[2-(propan-2-yloxy)phenyl]oxirane
  • 4-(Cyclobutylamino)-2-(2,2-dimethyl-1,3-dioxolan-4-yl)butan-1-ol
  • Methyl 1,2-dihydro-2-oxopyrazolo[1,5-a]pyridine-6-carboxylate
  • 2-Fluoro-2-[5-(trifluoromethyl)thiophen-3-yl]acetic acid
  • Methyl 4-amino-4-(3-ethylthiophen-2-yl)butanoate
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