Methyl Piperidine-2-carboxylate

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Names

[ CAS No. ]:
32559-18-5

[ Name ]:
Methyl Piperidine-2-carboxylate

[Synonym ]:
MFCD00192316
piperidine-2-carboxylic acid methyl ester hydrochloride
2-Piperidinecarboxylic acid, methyl ester, hydrochloride (1:1)
methyl piperidine-2-carboxylate hydrochloride
Methyl 2-piperidinecarboxylate hydrochloride (1:1)
L-pipecolic acid methyl ester hydrochloride
Methyl pipecolinate hydrochloride
DL-pipecolic acid methyl ester hydrochloride
Methyl 2-piperidinecarboxylate hydrochloride
(S)-pipecolic acid methyl ester hydrochloride
2-piperidine-carboxylic acid methyl ester hydrochloride
Methy pipecolinate HCl
Methyl Piperidine-2-carboxylate

Chemical & Physical Properties

[ Boiling Point ]:
235.3ºC at 760 mmHg

[ Melting Point ]:
205ºC (dec.)(lit.)

[ Molecular Formula ]:
C7H14ClNO2

[ Molecular Weight ]:
179.645

[ Flash Point ]:
96.1ºC

[ Exact Mass ]:
179.071304

[ PSA ]:
38.33000

[ LogP ]:
1.43230

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2933399090

Precursor & DownStream

Precursor

  • Methanol
  • Pipecolic acid
  • 2-Pyridinecarboxylicacid,methylester,1-oxide(9CI)

DownStream

  • L(-)-Pipecolinic acid
  • H-D-HomoPhe-OH
  • 1-Boc-2-piperidinecarbaldehyde
  • 2-Piperidinecarboxamide
  • METHYL1-BENZYL-PIPERIDINE-2-CARBOXYLATE
  • N-methylpiperidine-2-carboxamide

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Aldehyde-based racemization in the dynamic kinetic resolution of N-heterocyclic a-amino esters using Candida Antarctica lipase A. Liljeblad A, et al.

Tetrahedron 60(3) , 671-677, (2004)

Enantioselective lipase-catalyzed reactions of methyl pipecolinate: transesterification and N-acylation. Liljeblad, A, et al.

Tetrahedron Lett. 43(13) , 2471-2474, (2002)

The α-effect in cyclic secondary amines: new scaffolds for iminium ion accelerated transformations. Brazier JB, et al.

Tetrahedron 65(48) , 9961-9966, (2009)


More Articles

Related Compounds

  • Ethyl N-methyl piperidine-2-carboxylate
  • ETHYL 6-METHYLPIPERIDINE-2-CARBOXYLATE
  • 2-Piperidinecarboxylic acid, 2-Methyl-, ethyl ester
  • ethyl 2-methylpiperidine-2-carboxylate
  • 2-Piperidinecarboxylic acid, 2-Methyl-, Methyl ester
  • 2-Piperidinecarboxylicacid, 1-methyl-, methyl ester
  • 4-METHYL-PIPERIDINE-2-CARBOXYLIC ACID METHYL ESTER
  • 2-{3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-4-methylpentanamido}butanoic acid
  • 1-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methylpentanoyl]-4,4-difluoropyrrolidine-3-carboxylic acid
  • 2-[N-benzyl-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]acetic acid
  • 3-(2-Hydroxypropyl)-2,2-dimethyloxolane-3-carbaldehyde
  • 8-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]butanamido}octanoic acid
  • 3-[2-(4-formyl-3-methyl-1H-pyrazol-1-yl)phenyl]prop-2-ynoic acid
  • 1-[(Cyclohex-3-en-1-yl)methyl]cyclobutane-1-carbaldehyde
  • 2,2-Dimethyl-3-(thiolan-2-yl)propanal
  • 5-(3-Ethoxyphenyl)-2-ethylpiperidin-3-amine
  • 10-(2,2-Dimethylpropyl)-2,6-dioxa-9-azaspiro[4.5]decane
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