Nickel(2+) acetylacetonate

Suppliers

Names

[ CAS No. ]:
3264-82-2

[ Name ]:
Nickel(2+) acetylacetonate

[Synonym ]:
Nickel(II) Acetylacetonate
anhydrous nickel acetylacetonate
3-Penten-2-one, 4-hydroxy-, nickel(2+) salt, (3Z)- (2:1)
Acetylacetonenickel
Nickel bis(acetylacetonate)
2,4-Pentanedione nickel(II) derivative
NICKEL PENTANEDIONATE
NICKEL ACETYLACETONATE
EINECS 221-875-7
Nickel(2+) bis[(2Z)-4-oxo-2-penten-2-olate]
MFCD00000024
Acetylacetonate nickel
Nickel(2+) bis[(2Z)-4-oxopent-2-en-2-olate]
Bis(acetylacetonato)nickel(II)
Nickel(2+) acetylacetonate
Acetylacetonato nickel
Bis(2,4-pentanedionato)nickel(II)
Nickel acetonylacetonate

Chemical & Physical Properties

[ Density]:
0,145 g/cm3

[ Boiling Point ]:
220 °C (11 mmHg)

[ Melting Point ]:
230 °C (dec.)(lit.)

[ Molecular Formula ]:
C10H14NiO4

[ Molecular Weight ]:
256.909

[ Flash Point ]:
>200°C

[ Exact Mass ]:
256.024567

[ PSA ]:
52.60000

[ LogP ]:
1.92020

[ Index of Refraction ]:
1.57-1.64

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SA2100000
CHEMICAL NAME :
2,4-Pentanedione, nickel(II) deriv.
CAS REGISTRY NUMBER :
3264-82-2
LAST UPDATED :
199712
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C10-H14-Ni-O4
MOLECULAR WEIGHT :
256.95
WISWESSER LINE NOTATION :
1V1V1 &-NI-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
125 mg/kg
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,231,1952 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5635 No. of Facilities: 274 (estimated) No. of Industries: 2 No. of Occupations: 7 No. of Employees: 3418 (estimated) No. of Female Employees: 1678 (estimated)

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H317-H350

[ Precautionary Statements ]:
P201-P280-P301 + P312 + P330-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R40;R43

[ Safety Phrases ]:
53-36/37/39-45-36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
SA2100000

[ HS Code ]:
29420000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Nickel-acetic acid (1:1)
  • 2,4-Pentandione
  • trans-[Ni(acetylacetonato)2(PMe2Ph)2]
  • nickel methanolate
  • 4-hydroxypent-3-en-2-one

DownStream

  • P-TOLYLMAGNESIUM BROMIDE
  • Bis(triphenylphosphine)dicarbonylnickel
  • 2,4-Pentandione
  • Nickel-triphenylphosphine (1:4)
  • Tetrakis(triphenylphosphite)nickel(0)
  • (4-Chloro-3-fluorophenyl)acetonitrile
  • 3,3-bis(hydroxymethyl)-4-methoxybutan-2-one
  • nickel carbonyl
  • (2,4-diphenyl-1H-pyrrol-3-yl)-phenylmethanone

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Synthesis and Structural Evolution of Nickel-Cobalt Nanoparticles Under H2 and CO2.

Small 11 , 3045-53, (2015)

Bimetallic nanoparticle (NP) catalysts are interesting for the development of selective catalysts in reactions such as the reduction of CO2 by H2 to form hydrocarbons. Here the synthesis of Ni-Co NPs ...

Effect of component distribution and nanoporosity in CuPt nanotubes on electrocatalysis of the oxygen reduction reaction.

ChemSusChem 8(3) , 486-94, (2015)

Pt-based bimetallic electrocatalysts hold great potential in the oxygen reduction reaction (ORR) in current fuel-cell prototypes. However, they also face challenges from drastic dealloying of less-nob...

Ni3C-assisted growth of carbon nanofibres 300 °C by thermal CVD.

Nanotechnology 25(32) , 325602, (2014)

Ni-assisted thermal chemical vapor deposition (TCVD) is one of the most common techniques for the growth of carbon nanofibres/nanotubes (CNFs/CNTs). However, some fundamental issues related to the cat...


More Articles

Related Compounds

  • Nickel(2+),tris(1,2-ethanediamine-kN1,kN2)-, chloride (1:2), (OC-6-11)-
  • Nickel(2+),hexaammine-, dibromide, (OC-6-11)- (9CI)
  • nickel(2+) trifluoroacetate
  • nickel(2+),tributylphosphane
  • Nickel(2+) bis(4-methylbenzenesulfonate)
  • Nickel(2+) bis{(2-methyl-2-propanyl)[(1E)-N-(2-methyl-2-propanyl)ethanimidoyl]azanide}
  • Sodium;[2-[[6-hexadecoxy-3,4-dihydroxy-5-(pentanoylamino)oxan-2-yl]methoxymethyl]-3-hydroxy-2-(hydroxymethyl)propyl] sulfate
  • (3-Cyclopropoxy-2-methylphenyl)(methyl)sulfane
  • (2S)-2-amino-3-methylbutanenitrile hydrochloride
  • N-(5-cyclopropyl-1,3,4-thiadiazol-2-yl)-2-oxo-4aH-quinoline-4-carboxamide
  • Ethyl 5-hydroxy-2-(1-phenylethyl)-2-azabicyclo[2.2.2]octane-3-carboxylate
  • (5-Acetyl-1,3-phenylene)diboronicacid
  • 6-benzyl-1,3-dimethyl-5,7,8,8a-tetrahydro-4aH-pyrimido[4,5-d]pyrimidine-2,4-dione
  • 2-(3-Methylbutyl)piperidine hydrochloride
  • 3-(1,2,4-Oxadiazol-5-yl)propan-1-amine hydrochloride
  • 1-[4-(1-Aminoethyl)phenyl]-3,3-diethylurea hydrochloride
The content on this webpage is sourced from various professional data sources. If you have any questions or concerns regarding the content, please feel free to contact service1@chemsrc.com.