Methyl 3-bromopropanoate

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Names

[ CAS No. ]:
3395-91-3

[ Name ]:
Methyl 3-bromopropanoate

[Synonym ]:
Methyl 3-Bromopropionate
Methyl 3-bromopropanoate
Propionic acid, 3-bromo-, methyl ester (8CI)
Propanoic acid, 3-bromo-, methyl ester
Propanoic acid,3-bromo-,methyl ester
MFCD00000250
EINECS 222-247-5
Propionic acid,3-bromo-,methyl ester
Methyl β-bromopropionate
3-Bromopropanoic acid methyl ester
3-Bromopropionic Acid Methyl Ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
166.5±0.0 °C at 760 mmHg

[ Melting Point ]:
75°C

[ Molecular Formula ]:
C4H7BrO2

[ Molecular Weight ]:
167.001

[ Flash Point ]:
75.0±0.0 °C

[ Exact Mass ]:
165.962936

[ PSA ]:
26.30000

[ LogP ]:
1.15

[ Vapour Pressure ]:
1.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.453

[ Storage condition ]:
Store at R.T.

[ Water Solubility ]:
Immiscible

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UA2451790
CHEMICAL NAME :
Propanoic acid, 3-bromo-, methyl ester
CAS REGISTRY NUMBER :
3395-91-3
LAST UPDATED :
199710
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C4-H7-Br-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - ataxia Vascular - regional or general arteriolar or venous dilation
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570991

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ WGK Germany ]:
3

[ RTECS ]:
UA2451790

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
29159080

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl propanoate
  • acrylic acid methyl ester
  • 3-Bromopropanoic acid
  • Methanol
  • β-Propiolactone
  • 4-Methoxy-4-oxobutanoic acid
  • alpha-Bromostyrene
  • Acrylic acid

DownStream

  • Ethyl 3-(diethoxyphosphoryl)propanoate
  • Methyl 3-[(3-methoxy-3-oxopropyl)phenylamino]propanoate
  • 4-Bromo-2-methyl-2-butanol
  • 3,4-Dihydro-2H-pyrido(1,2-a)pyrimidin-2-one
  • (3-methoxy-3-oxopropyl)-trimethylazanium,bromide
  • METHYL 3-NITROPROPIONATE
  • 2-Thioxo-3-thiazolidinepropanoic acid methyl est
  • methyl 3-(2-formylpyrrol-1-yl)propanoate
  • Methyl 3-phenylpropanoate
  • Bromo(triethyl)silane

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Samarium diiodide promoted spirolactonization of cycloalkanones. Hua Z, et al.

Tetrahedron 47(34) , 7037-7044, (1991)


More Articles

Related Compounds

  • Methyl 3-bromopropanoate
  • Methyl 3-bromo-2-methylpropanoate
  • methyl 3-amino-3-pyridin-3-ylprop-2-enoate
  • methyl 3-hydroxy-2,2-dimethoxy-3-phenyl-propanoate
  • Methyl 3-bromo-5-(((trifluoromethyl)sulfonyl)-oxy)-4-(trimethylsilyl)benzoate
  • methyl 3,4,5-tridodecoxybenzoate
  • Propyl 2-amino-3-(furan-3-yl)propanoate;hydrochloride
  • 2,7-Diazaspiro[3.5]nonane-7-sulfonyl fluoride
  • 5-Oxaspiro[3.4]oct-7-ene
  • 8-Bromo-7-methylimidazo[1,2-c]pyrimidin-5-ol
  • 2,5-Dimethyl-4-propylpiperidine
  • rac-(1R,2R)-2-(4-methylpentyl)cyclopentan-1-ol
  • 1-Chloro-4-ethynyl-2,5-dimethylbenzene
  • 1-(3-methyl-2,3-dihydro-1,4-benzoxazin-4-yl)prop-2-en-1-one
  • 7-Chloro-4-iodobenzo[d]thiazole
  • 3-Ethyl-2,6-dimethoxybenzenesulfonic acid
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