3-Bromo-4-methylpyridine

Suppliers

Names

[ CAS No. ]:
3430-22-6

[ Name ]:
3-Bromo-4-methylpyridine

[Synonym ]:
4-Methyl-3-bromopyridine
3-Bromo-4-methylpyridine
3-Bromo-4-methyl-pyridine
3-Bromo-4-picoline
Pyridine, 3-bromo-4-methyl-
3-brom-4-methylpyridin
bromo-3 methyl-4 pyridine
MFCD00082592

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
198.8±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H6BrN

[ Molecular Weight ]:
172.023

[ Flash Point ]:
74.1±21.8 °C

[ Exact Mass ]:
170.968353

[ PSA ]:
12.89000

[ LogP ]:
2.21

[ Vapour Pressure ]:
0.5±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.553

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S2636

[ RIDADR ]:
Cool, dry,tightly closed

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2933399090

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Picoline
  • 1(4H)-Pyridinecarboxylic acid, 3-bromo-4-methyl-, phenyl ester
  • 3-Bromopyridine
  • methyl iodide
  • Lithium diisopropylamide

DownStream

  • (4-Methylpyridin-3-yl)methanol
  • Ethyl 2-(3-bromopyridin-4-yl)acetate
  • 4-Methylnicotinic acid
  • Methyl 4-methylnicotinate
  • 4-Methylnicotinaldehyde
  • TERT-BUTYL 2-CHLOROPYRIDIN-4-YLCARBAMATE
  • 3-BROMO-4-(3-HYDROXYPROPYL)PYRIDINE
  • 4-Picoline
  • 4-Methylnicotinonitrile
  • 3-Ethynyl-4-methylpyridine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Tricyclic pyridones as functionally selective human GABAA alpha 2/3 receptor-ion channel ligands.

Bioorg. Med. Chem. Lett. 14(7) , 1679-82, (2004)

A series of tricyclic pyridones has been evaluated as benzodiazepine site ligands with functional selectivity for the alpha(3) over the alpha(1) containing subtype of the human GABA(A) receptor ion ch...

Substituted 4-(2,2-diphenylethyl)pyridine-N-oxides as phosphodiesterase-4 inhibitors: SAR study directed toward the improvement of pharmacokinetic parameters.

Bioorg. Med. Chem. Lett. 12(20) , 3009-13, (2002)

A detailed SAR study directed toward the optimization of pharmacokinetic parameters for analogues of L-791,943 is reported. The introduction of a soft metabolic site on this structure permitted the id...

Total synthesis of ascididemin via anionic cascade ring closure.

Chem. Commun. (Camb.) 48(72) , 9092-4, (2012)

A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2...


More Articles


Related Compounds

  • 3-Bromo-4-methylpyridine
  • 3-bromo-4-methylpyridine N-oxide
  • 2-HYDROXY-3-BROMO-4-METHYLPYRIDINE
  • 3-bromo-4-methylpyridine-2,5-diamine
  • 2-(Benzyloxy)-3-bromo-4-methylpyridine
  • 3-bromo-4-methylpyridine-2-carbonitrile
  • Methyl 2-((1-(4-propyl-1,2,3-thiadiazole-5-carbonyl)pyrrolidin-3-yl)thio)acetate
  • 1-[(4-BRomo-2-methylbenzene)sulfonyl]pyrrolidine
  • 3-Fluoro-3-(p-tolyl)butanoic acid
  • Methyl 4-(3-((2-methoxy-2-oxoethyl)thio)pyrrolidine-1-carbonyl)benzoate
  • [2,5-Difluoro-4-(4-methylphenyl)phenyl]boronic acid
  • 5-(2-Formylphenyl)picolinonitrile
  • 5-Bromo-2-[3-(2-methoxyethoxy)azetidin-1-yl]pyrimidine
  • 3,7-Dimethyloctan-1-amine hydrochloride
  • 4-(3-Methylpyrazin-2-yl)morpholine
  • [2-(3,5-Dichlorophenyl)propan-2-yl](methyl)amine
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