L-Thioproline

Suppliers

Names

[ CAS No. ]:
34592-47-7

[ Name ]:
L-Thioproline

[Synonym ]:
H-THZ-OH
L-Thiazolidine-4-car
(R)-4-Thiazolidinecarboxylic acid
EINECS 252-106-3
L-THC
THIAPROLINE
(4R)-4-Thiazolidinecarboxylic acid
(4R)-thiazolidine-4-carboxylic acid
1,3-Thiazolidine-2-carboxylic acid
Thiazolidinecarboxylic acid (VAN)
THIAZOLIDINECARBOXYLIC ACID
2-Thiazolidinecarboxylic acid
DL-Thiazolidinecarboxylic acid
L(-)-Thiazolidine-4-carboxylicacid
L(-)-Thiazolidine-4-Carboxylic Acid
L-Thiazolidine-4-carboxylic acid
H-L-THZ-OH
MFCD00005212
(4R)-1,3-Thiazolidine-4-carboxylic acid
L-4-Thiazolidinecarboxylic acid
L-Thioproline
thiazolidinecarboxylicacid
(R)-(-)-4-Thiazolidinecarboxylic acid
L- thiazolidine-4-carboxylic acid
THIOPROLINE
H-THIOPRO-OH
L-THIAPROLINE
(R)-Thiazolidine-4-carboxylic acid
(R)-(-)-Thiazolidine-4-carboxylic Acid
L-thiazoline-4-carboxylic acid
4-Thiazolidinecarboxylic acid, (4R)-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
350.3±37.0 °C at 760 mmHg

[ Melting Point ]:
190-200 °C (dec.)(lit.)

[ Molecular Formula ]:
C4H7NO2S

[ Molecular Weight ]:
133.169

[ Flash Point ]:
165.7±26.5 °C

[ Exact Mass ]:
133.019745

[ PSA ]:
74.63000

[ LogP ]:
-0.39

[ Vapour Pressure ]:
0.0±1.6 mmHg at 25°C

[ Index of Refraction ]:
1.566

[ Water Solubility ]:
28.5 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XJ5425500
CHEMICAL NAME :
4-Thiazolidinecarboxylic acid, L-
CAS REGISTRY NUMBER :
34592-47-7
LAST UPDATED :
199610
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C4-H7-N-O2-S
MOLECULAR WEIGHT :
133.18
WISWESSER LINE NOTATION :
T5M CSTJ EVQ -L

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
210 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FRXXBL French Demande Patent Document. (U.S. Patent and Trademark Office, Foreign Patents, Washington, DC 20231) Volume(issue)/page/year: #2547728
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
178 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00644

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S26-S36/37/39-S36

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
XJ5425500

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29341000

Synthetic Route

Precursor & DownStream

Precursor

  • Formaldehyde
  • L-cysteine
  • L-Cysteine hydrochloride anhydrous
  • (2S,3S)-2,3-dihydroxysuccinic acid compound with (R)-thiazolidine-4-carboxylic acid (1:1)
  • N-Boc-(R)-(-)-thiazolidine-4-carboxylic acid
  • Timonacic
  • DL-Cysteine Hydrochloride

DownStream

  • (4R)-3-Acetyl-1,3-thiazolidine-4-carboxylic acid
  • 4-Thiazolidinecarboxylicacid, methyl ester, hydrochloride (1:1)
  • N-Boc-(R)-(-)-thiazolidine-4-carboxylic acid
  • Folcisteine
  • L-cysteine
  • Timonacic
  • Pidotimod
  • 3-mercapto-2-(methylamino)propanoic acid hydrochloride
  • Telmesteine
  • 3-(1-oxidopyridin-6-yl)thiazolidine-4-carboxylic acid

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Three-dimensional quantitative structure-activity relationship analyses of substrates of the human proton-coupled amino acid transporter 1 (hPAT1).

Bioorg. Med. Chem. 19 , 6409-18, (2011)

The proton-coupled amino acid transporter hPAT1 has recently gained much interest due to its ability to transport small drugs thereby allowing their oral administration. A three-dimensional quantitati...

Design, synthesis and biological evaluation of 2-(substituted phenyl)thiazolidine-4-carboxylic acid derivatives as novel tyrosinase inhibitors.

Biochimie 94(2) , 533-40, (2012)

Herein we describe the design, synthesis and biological activities of 2-(substituted phenyl)thiazolidine-4-carboxylic acid derivatives as novel tyrosinase inhibitors. The target compounds 2a-2j were d...

Successful computer guided planned synthesis of (4R)-thiazolidine carboxylic acid and its 2-substituted analogues as urease inhibitors.

Mol. Divers. 10(2) , 223-31, (2006)

By using internal combinatorial library we were able to identify (4R)-thiazolidines carboxylic acid and its 2-substituted analogs as active inhibitors of urease. Molecular modeling and virtual screeni...


More Articles


Related Compounds

  • L-Thioproline
  • L-THIOPROLINE
  • L-Thioproline
  • L-THIOPROLINE
  • fmoc-l-thioproline
  • (-)-Boc-L-thioproline
  • 1-(Chloromethyl)-3-(2-fluoro-4-methoxyphenyl)bicyclo[1.1.1]pentane
  • 2-(2-Methoxypropan-2-yl)-2-methyloxirane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 6-Chloro-7-fluoro-1-benzofuran-2-carboxylic acid