L-Thioproline

Modify Date: 2024-01-02 15:42:07

L-Thioproline Structure
L-Thioproline structure
 Common Name L-Thioproline
CAS Number 34592-47-7 Molecular Weight 133.169
Density 1.4±0.1 g/cm3 Boiling Point 350.3±37.0 °C at 760 mmHg
Molecular Formula C4H7NO2S Melting Point 190-200 °C (dec.)(lit.)
MSDS Chinese USA Flash Point 165.7±26.5 °C
Symbol GHS06
GHS06		 Signal Word Danger

 Use of L-Thioproline


(R)-Thiazolidine-4-carboxylic acid is a proline derivative[1].

 Names

Name L-Thioproline
Synonym More Synonyms

 L-Thioproline Biological Activity

Description (R)-Thiazolidine-4-carboxylic acid is a proline derivative[1].
Related Catalog
In Vitro Amino acids and amino acid derivatives have been commercially used as ergogenic supplements. They influence the secretion of anabolic hormones, supply of fuel during exercise, mental performance during stress related tasks and prevent exercise induced muscle damage. They are recognized to be beneficial as ergogenic dietary substances[1].
References

[1]. Luckose F, et al. Effects of amino acid derivatives on physical, mental, and physiological activities. Crit Rev Food Sci Nutr. 2015;55(13):1793-1144.

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 350.3±37.0 °C at 760 mmHg
Melting Point 190-200 °C (dec.)(lit.)
Molecular Formula C4H7NO2S
Molecular Weight 133.169
Flash Point 165.7±26.5 °C
Exact Mass 133.019745
PSA 74.63000
LogP -0.39
Vapour Pressure 0.0±1.6 mmHg at 25°C
Index of Refraction 1.566
Water Solubility 28.5 g/L (20 ºC)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XJ5425500
CHEMICAL NAME :
4-Thiazolidinecarboxylic acid, L-
CAS REGISTRY NUMBER :
34592-47-7
LAST UPDATED :
199610
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C4-H7-N-O2-S
MOLECULAR WEIGHT :
133.18
WISWESSER LINE NOTATION :
T5M CSTJ EVQ -L

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
210 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FRXXBL French Demande Patent Document. (U.S. Patent and Trademark Office, Foreign Patents, Washington, DC 20231) Volume(issue)/page/year: #2547728
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
178 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00644

 Safety Information

Symbol GHS06
GHS06
Signal Word Danger
Hazard Statements H301-H312-H315-H319-H332-H335
Precautionary Statements P261-P280-P301 + P310-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R22
Safety Phrases S26-S36/37/39-S36
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS XJ5425500
Packaging Group III
Hazard Class 6.1(b)
HS Code 29341000

 Synthetic Route

Formaldehyde structure

Formaldehyde

CAS#:50-00-0

L-cysteine structure

L-cysteine

CAS#:52-90-4

~98%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Kaupp, Gerd; Schmeyers, Jens; Boy, Juergen Tetrahedron, 2000 , vol. 56, # 36 p. 6899 - 6911
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

L-Cysteine hydrochloride anhydrous structure

L-Cysteine hydr...

CAS#:52-89-1

~93%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Refouvelet; Pellegrini; Robert; Crini; Blacque; Kubicki Journal of Heterocyclic Chemistry, 2000 , vol. 37, # 6 p. 1425 - 1430
L-cysteine structure

L-cysteine

CAS#:52-90-4

~%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: US6605608 B1, ; US 6605608 B1
L-Cysteine hydrochloride anhydrous structure

L-Cysteine hydr...

CAS#:52-89-1

~%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Journal of Biological Chemistry, , vol. 114, p. 348 Journal of Biological Chemistry, , vol. 121, p. 542,545
(2S,3S)-2,3-dihydroxysuccinic acid compound with (R)-thiazolidine-4-carboxylic acid (1:1) structure

(2S,3S)-2,3-dih...

CAS#:114192-99-3

~78%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Shiraiwa, Tadashi; Kataoka, Kazuo; Kurokawa, Hidemoto Chemistry Letters, 1987 , p. 2041 - 2042
N-Boc-(R)-(-)-thiazolidine-4-carboxylic acid structure

N-Boc-(R)-(-)-t...

CAS#:51077-16-8

~%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Journal of Organic Chemistry, , vol. 74, # 11 p. 4289 - 4297
(R)-1-aza-3-oxa-7-thiabicyclo(3.3.0)-octan-4-one structure

(R)-1-aza-3-oxa...

CAS#:164986-91-8

~%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Tetrahedron, , vol. 51, # 10 p. 3015 - 3024
Timonacic structure

Timonacic

CAS#:444-27-9

~%

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Bulletin of the Chemical Society of Japan, , vol. 65, # 1 p. 267 - 273
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

DL-Cysteine Hydrochloride structure

DL-Cysteine Hyd...

CAS#:10318-18-0

~%

Timonacic structure

Timonacic

CAS#:444-27-9

L-Thioproline Structure

L-Thioproline

CAS#:34592-47-7

Literature: Bulletin of the Chemical Society of Japan, , vol. 60, # 9 p. 3277 - 3284

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles27

More Articles
Three-dimensional quantitative structure-activity relationship analyses of substrates of the human proton-coupled amino acid transporter 1 (hPAT1).

Bioorg. Med. Chem. 19 , 6409-18, (2011)

The proton-coupled amino acid transporter hPAT1 has recently gained much interest due to its ability to transport small drugs thereby allowing their oral administration. A three-dimensional quantitati...

Design, synthesis and biological evaluation of 2-(substituted phenyl)thiazolidine-4-carboxylic acid derivatives as novel tyrosinase inhibitors.

Biochimie 94(2) , 533-40, (2012)

Herein we describe the design, synthesis and biological activities of 2-(substituted phenyl)thiazolidine-4-carboxylic acid derivatives as novel tyrosinase inhibitors. The target compounds 2a-2j were d...

Successful computer guided planned synthesis of (4R)-thiazolidine carboxylic acid and its 2-substituted analogues as urease inhibitors.

Mol. Divers. 10(2) , 223-31, (2006)

By using internal combinatorial library we were able to identify (4R)-thiazolidines carboxylic acid and its 2-substituted analogs as active inhibitors of urease. Molecular modeling and virtual screeni...

 Synonyms

H-THZ-OH
L-Thiazolidine-4-car
(R)-4-Thiazolidinecarboxylic acid
EINECS 252-106-3
L-THC
THIAPROLINE
(4R)-4-Thiazolidinecarboxylic acid
(4R)-thiazolidine-4-carboxylic acid
1,3-Thiazolidine-2-carboxylic acid
Thiazolidinecarboxylic acid (VAN)
THIAZOLIDINECARBOXYLIC ACID
2-Thiazolidinecarboxylic acid
DL-Thiazolidinecarboxylic acid
L(-)-Thiazolidine-4-carboxylicacid
L(-)-Thiazolidine-4-Carboxylic Acid
L-Thiazolidine-4-carboxylic acid
H-L-THZ-OH
MFCD00005212
(4R)-1,3-Thiazolidine-4-carboxylic acid
L-4-Thiazolidinecarboxylic acid
L-Thioproline
thiazolidinecarboxylicacid
(R)-(-)-4-Thiazolidinecarboxylic acid
L- thiazolidine-4-carboxylic acid
THIOPROLINE
H-THIOPRO-OH
L-THIAPROLINE
(R)-Thiazolidine-4-carboxylic acid
(R)-(-)-Thiazolidine-4-carboxylic Acid
L-thiazoline-4-carboxylic acid
4-Thiazolidinecarboxylic acid, (4R)-
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