PCB-153

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Names

[ CAS No. ]:
35065-27-1

[ Name ]:
PCB-153

[Synonym ]:
2,2',4,4',5,5'-heptachlorobiphenyl
PCB 153
2,2',3,3',5,6'-HEXACHLOROBIPHENYL
HCBP
biphenyl, 2,2’,4,4’,5,5’-hexachloro-
CB-153
2,2',4,4',5,5'-Hexachloro-1,1'-biphenyl
2,2',4,4',5,5'-PCB
1,1'-Biphenyl,2,2',4,4',5,5'-hexachloro
2,2',4,4',5,5'-Hexachloro-1,1'-biphenyl (9CI)
PCB-153
Biphenyl, 2,2',4,4',5,5'-hexachloro-
2,2',4,4',5,5'-Hexachlorobiphenyl
1,1'-Biphenyl, 2,2',4,4',5,5'-hexachloro-
1,2,4-trichloro-5-(2,4,5-trichlorophenyl)benzene
2,4,5,2',4',5'-Hexachlorobiphenyl
2,2',4,4',5,5'-hexachloromobiphenyl
2,2′,4,4′,5,5′-Hexachlorobiphenyl

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
396.2±37.0 °C at 760 mmHg

[ Melting Point ]:
103-104ºC

[ Molecular Formula ]:
C12H4Cl6

[ Molecular Weight ]:
360.878

[ Flash Point ]:
193.2±23.9 °C

[ Exact Mass ]:
357.844421

[ LogP ]:
6.83

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.627

[ Storage condition ]:
2-8°C

[ Stability ]:
Thermally stable and resistant to both oxidation and biological degradation.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DV5350000
CHEMICAL NAME :
1,1'-Biphenyl, 2,2',4,4',5,5'-hexachloro-
CAS REGISTRY NUMBER :
35065-27-1
LAST UPDATED :
199712
DATA ITEMS CITED :
19
MOLECULAR FORMULA :
C12-H4-Cl6
MOLECULAR WEIGHT :
360.86

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
370 mg/kg/30D-I
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in thymus weight Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
322 mg/kg/13W-C
TOXIC EFFECTS :
Gastrointestinal - other changes Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
150 mg/kg/3D-I
TOXIC EFFECTS :
Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other esterases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other Enzymes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
960 mg/kg/4W-I
TOXIC EFFECTS :
Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases Biochemical - Metabolism (Intermediary) - porphyrin including bile pigments
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
1470 mg/kg/21D-C
TOXIC EFFECTS :
Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3650 mg/kg/104W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
50 mg/kg
SEX/DURATION :
female 8-18 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - biochemical and metabolic
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
448 mg/kg
SEX/DURATION :
female 10-16 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
112 mg/kg
SEX/DURATION :
female 10-16 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - biochemical and metabolic
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
448 mg/kg
SEX/DURATION :
female 10-16 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain) Reproductive - Effects on Newborn - behavioral Reproductive - Effects on Newborn - physical
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
120 mg/kg
SEX/DURATION :
female 1-6 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
78 mg/kg
SEX/DURATION :
female 5-21 day(s) after conception lactating female 22 day(s) post-birth
TOXIC EFFECTS :
Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
200 mg/kg
SEX/DURATION :
female 13-21 day(s) after conception lactating female 24 day(s) post-birth
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - urogenital system
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
271 mg/kg
SEX/DURATION :
female 10 day(s) after conception
TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1080 mg/kg
SEX/DURATION :
female 45-62 day(s) after conception
TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects
TYPE OF TEST :
DNA adduct

MUTATION DATA

TEST SYSTEM :
Rodent - mouse
DOSE/DURATION :
36400 ug/kg/5D
REFERENCE :
CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 27,99,1979

Safety Information

[ Symbol ]:

GHS08, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H373-H410

[ Precautionary Statements ]:
P273-P391-P501

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;N: Dangerous for the environment;Xn: Harmful;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
16-26-33-36-61-60-35-62-29-9

[ RIDADR ]:
UN 2315

[ Packaging Group ]:
II

[ Hazard Class ]:
9

[ HS Code ]:
2903999090

Precursor & DownStream

Precursor

  • Bromobenzene
  • 1,2,4,5-Tetrachlorobenzene
  • Benzene,1,2,4-trichloro-5-iodo-
  • 2,2',3,4,4',5,5'-PCB
  • 2,4,5-Trichloroaniline
  • 1,2,4-Trichlorobenzene
  • 2,2',5,5'-Tetrachloro-4,4'-biphenyldiamine

DownStream

  • OCTACHLOROBIPHENYL
  • 2,3,7,8-Tetrachlorodibenzofuran
  • Biphenyl
  • Bicyclohexane
  • 1-phenylcyclohex-1-ene
  • Cyclohexylbenzene
  • pcb 1
  • 2,4,5-Trichlorobiphenyl
  • PCB 7
  • 2,2',4,5-tetrachlorobiphenyl

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Cross-omics gene and protein expression profiling in juvenile female mice highlights disruption of calcium and zinc signalling in the brain following dietary exposure to CB-153, BDE-47, HBCD or TCDD.

Toxicology 321 , 1-12, (2014)

The present study assessed if eating a diet of fish, spiked with persistent organic pollutants (POPs), affects gene and protein expression in the maturing mouse brain. Juvenile female Balb/c mice (22 ...

Associations of accumulated exposure to persistent organic pollutants with serum lipids and obesity in an adult cohort from Southern Spain.

Environ. Pollut. 195 , 9-15, (2014)

The aim of this research was to study the association of the accumulated human exposure to persistent organic pollutants with serum lipid levels and obesity, in a cohort of 298 adults. In the multivar...

Temporal dynamics of circulating persistent organic pollutants in a fasting seabird under different environmental conditions.

Environ. Sci. Technol. 46(18) , 10287-94, (2012)

Temporal dynamics of persistent organic pollutants (POPs) were examined in fasting common eider (Somateria mollissima) females in one subarctic (68° N; over 5 years) and one high arctic colony (78° N;...


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