Tris(pentafluoroethyl)amine

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Names

[ CAS No. ]:
359-70-6

[ Name ]:
Tris(pentafluoroethyl)amine

[Synonym ]:
MFCD00166270
1,1,2,2,2-pentafluoro-N,N-bis(1,1,2,2,2-pentafluoroethyl)ethanamine
1,1,2,2,2-Pentafluoro-N,N-bis(pentafluoroethyl)ethanamine
EINECS 206-632-5
Ethanamine, 1,1,2,2,2-pentafluoro-N,N-bis(1,1,2,2,2-pentafluoroethyl)-

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
70.3±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C6F15N

[ Molecular Weight ]:
371.047

[ Flash Point ]:
-3.7±25.9 °C

[ Exact Mass ]:
370.979126

[ PSA ]:
3.24000

[ LogP ]:
12.72

[ Vapour Pressure ]:
129.7±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.262

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KH2155170
CHEMICAL NAME :
Ethanamine, N,N-bis(pentafluoroethyl)-1,1,2,2,2-pentalfluoro-
CAS REGISTRY NUMBER :
359-70-6
BEILSTEIN REFERENCE NO. :
1813672
LAST UPDATED :
199709
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-F15-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1420 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(6),26,1974
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1340 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(6),26,1974

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
KH2155170

[ HS Code ]:
2921199090

Synthetic Route

Precursor & DownStream

Precursor

  • Triethylamine
  • b-Alanine, N,N-diethyl-, methylester
  • methyl 3-(diethylamino)-2-methylpropanoate
  • methyl 2-diethylamino-propionate
  • N-(2-Hydroxyethyl)piperazine
  • 2-(Diethylamino)ethanol
  • Tetraethylammonium Iodide
  • HYDROFLUORIC ACID
  • 1-Piperazineaceticacid,-alpha-,4-dimethyl-,methylester(9CI)
  • Cobalt(Iii) Fluoride

DownStream

  • 1,1-difluoro-N-(1,1,2,2,2-pentafluoroethyl)methanimine
  • 2,2,2-trifluoro-N-(1,1,2,2,2-pentafluoroethyl)ethanimidoyl fluoride

Customs

[ HS Code ]: 2921199090

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Organic reactions without an organic medium. Utilization of perfluorotriethylamine as a reaction medium. Nakano H and Kitazume T.

Green Chem. 1(1) , 21-22, (1999)

Thermal decomposition of halon alternatives. Yamamoto T, et al.

Chemosphere 35(3) , 643-54, (1997)

The behavior of bubbles in perfluorotriethylamine under the effect of strong electric fields. Korobeinikov SM, et al.

High Temp. 39(6) , 821-25, (2001)


More Articles


Related Compounds

  • TETRAETHYLAMMONIUM TRIS(PENTAFLUOROETHYL)TRIFLUOROPHOSPHATE
  • guanidinium tris(pentafluoroethyl)trifluorophosphate
  • triethyloxonium tris(pentafluoroethyl)trifluorophosphate
  • hexamethylguanidinium tris(pentafluoroethyl)trifluorophosphate
  • TETRAMETHYLAMMONIUM TRIS(PENTAFLUOROETHYL)TRIFLUOROPHOSPHATE
  • nsc-747273
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • (2,5-dioxopyrrolidin-1-yl) 2-[[(3S,5R,8R,9S,10S,12R,13S,14S,17R)-12,14-dihydroxy-10,13-dimethyl-17-(5-oxo-2H-furan-3-yl)-1,2,3,4,5,6,7,8,9,11,12,15,16,17-tetradecahydrocyclopenta[a]phenanthren-3-yl]oxy]acetate
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide