(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL-

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Names

[ Name ]:
(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL-

[Synonym ]:
(1,2-dihydronaphthalen-4-yloxy)trimethylsilane
(3,4-dihydronaphthalen-1-yloxy)trimethylsilane
(3,4-dihydro-1-naphthalenyloxy)(trimethyl)silane
3,4-Dihydro-1-(trimethylsilyloxy)naphthalene
(3,4-Dihydro-1-naphthyloxy)trimethylsilane
MFCD03093969
3,4-dihydronaphthalen-1(2H)-one trimethylsilyl enol ether

Chemical & Physical Properties

[ Density]:
0.983 g/mL at 25ºC(lit.)

[ Boiling Point ]:
63-65ºC0.01 mm Hg(lit.)

[ Molecular Formula ]:
C₁₃H₁₈OSi

[ Molecular Weight ]:
218.36700

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
218.11300

[ PSA ]:
9.23000

[ LogP ]:
3.82520

[ Index of Refraction ]:
n20/D 1.5287(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Chlorotrimethylsilane
3,4-Dihydronaphthalen-1(2H)-one
Trimethylsilyl trifluoromethanesulfonate
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
1-methoxy-1-trimethylsilyloxypropene
Trimethylsilyl acetate
1(4H)-Naphthalenone (en)
trimethyl(1,2,4-triazol-1-ylmethyl)silane

DownStream

1-Naphthalenol
(2R)-2-benzyl-3,4-dihydro-2H-naphthalen-1-one
3,4-Dihydronaphthalen-1(2H)-one
2-(2-Carboxyethyl)benzoic acid
2-trimethylsilyloxy-3,4-dihydro-2H-naphthalen-1-one
1(2H)-Naphthalenone,2-chloro-3,4-dihydro-
2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers.

Chem. Commun. (Camb.) (47) , 5049-51, (2007)

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone sub...

3,4-Dihydro-1-(2-mercaptophenyl)-4,4,6-trimethyl-2(1H)-pyrimidinethione
3,4-Dihydro-1-(m-hydroxyphenyl)-4,4,6-trimethyl-2(1H)-pyrimidinethione
3,4-Dihydro-1-(o-nitrophenyl)-4,4,6-trimethyl-2(1H)-pyrimidinethione
3,4-Dihydro-1,11-dimethylchrysene
1H-3,4-dihydro-1,3,4-trimethyl-2-oxopyrimidinediylium sulphate
2(1H)-Quinolinone,3,4-dihydro-1,6,7-trimethyl-
5-Phenyl-3,4,5,7,9,16-hexaazatetracyclo[7.7.0.0^{2,6}.0^{10,15}]hexadeca-1(16),2(6),3,7,10(15),11,13-heptaene
N-{[5-(3,5-dimethyl-1,2-oxazol-4-yl)furan-2-yl]methyl}-2,1,3-benzothiadiazole-4-sulfonamide
5-benzoyl-N-({1-[(1-benzyl-5-oxopyrrolidin-3-yl)methyl]-1H-1,2,3-triazol-4-yl}methyl)-2,3-dihydro-1H-pyrrolizine-1-carboxamide
3-{[1-(4-fluorophenyl)-1H-1,2,3-triazol-4-yl](4-hydroxy-2-oxo-2H-chromen-3-yl)methyl}-4-hydroxy-2H-chromen-2-one
(5,7-Dibromoquinolin-8-yl) 2-oxochromene-6-sulfonate
Methyl 1-[2-[2-(3,4-dimethoxyphenyl)ethylamino]-2-oxoethyl]-5,7-difluoro-4-oxoquinoline-3-carboxylate
4-(3,4-dimethoxyphenyl)-1-phenyl-5-(1H-pyrrol-1-yl)-1H-1,2,3-triazole
4-(4-methoxyphenyl)-1-phenyl-5-(1H-pyrrol-1-yl)-1H-1,2,3-triazole
4-(4-methylphenyl)-1-phenyl-5-(1H-pyrrol-1-yl)-1H-1,2,3-triazole
1-phenyl-5-(1H-pyrrol-1-yl)-4-(3,4,5-trimethoxyphenyl)-1H-1,2,3-triazole

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