(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL-
Suppliers
Names
[ CAS No. ]:
38858-72-9
[ Name ]:
(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL-
[Synonym ]:
(1,2-dihydronaphthalen-4-yloxy)trimethylsilane
(3,4-dihydronaphthalen-1-yloxy)trimethylsilane
(3,4-dihydro-1-naphthalenyloxy)(trimethyl)silane
3,4-Dihydro-1-(trimethylsilyloxy)naphthalene
(3,4-Dihydro-1-naphthyloxy)trimethylsilane
MFCD03093969
3,4-dihydronaphthalen-1(2H)-one trimethylsilyl enol ether
Chemical & Physical Properties
[ Density]:
0.983 g/mL at 25ºC(lit.)
[ Boiling Point ]:
63-65ºC0.01 mm Hg(lit.)
[ Molecular Formula ]:
C13H18OSi
[ Molecular Weight ]:
218.36700
[ Flash Point ]:
>230 °F
[ Exact Mass ]:
218.11300
[ PSA ]:
9.23000
[ LogP ]:
3.82520
[ Index of Refraction ]:
n20/D 1.5287(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Chem. Commun. (Camb.) (47) , 5049-51, (2007)
Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone sub...