(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL-

Modify Date: 2024-01-04 19:22:25

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure
(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- structure
Common Name (3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL-
CAS Number 38858-72-9 Molecular Weight 218.36700
Density 0.983 g/mL at 25ºC(lit.) Boiling Point 63-65ºC0.01 mm Hg(lit.)
Molecular Formula C13H18OSi Melting Point N/A
MSDS Chinese Flash Point >230 °F
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 3,4-dihydronaphthalen-1-yloxy(trimethyl)silane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.983 g/mL at 25ºC(lit.)
Boiling Point 63-65ºC0.01 mm Hg(lit.)
Molecular Formula C13H18OSi
Molecular Weight 218.36700
Flash Point >230 °F
Exact Mass 218.11300
PSA 9.23000
LogP 3.82520
Index of Refraction n20/D 1.5287(lit.)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases 36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
HS Code 2931900090

 Synthetic Route

~99%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Literature: Roy, Bhairab N; Singh, Girij P; Lathi, Piyush S; Agrawal, Manoj K; Mitra, Rangan; Trivedi, Anurag Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013 , vol. 52, # 10 p. 1299 - 1312

~96%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Literature: Barlow, James W.; McHugh, Aengus P.; Woods, Orla; Walsh, John J. European Journal of Medicinal Chemistry, 2011 , vol. 46, # 5 p. 1545 - 1554

~93%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Literature: Song, Jinhua J.; Tan, Zhulin; Reeves, Jonathan T.; Fandrick, Daniel R.; Yee, Nathan K.; Senanayake, Chris H. Organic Letters, 2008 , vol. 10, # 5 p. 877 - 880

~87%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Literature: Kita, Yasuyuki; Yasuda, Hitoshi; Haruta, Jun-ichi; Segawa, Jun; Tamura, Yasumitsu Synthesis, 1982 , # 12 p. 1089 - 1091

~50%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Literature: Coumbarides, Gregory S.; Eames, Jason; Suggate, Michael J.; Weerasooriya, Neluka Journal of Labelled Compounds and Radiopharmaceuticals, 2006 , vol. 49, # 7 p. 641 - 652

~55%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Literature: Bell, Craig H.; Pinhey, John T.; Sternhell, Sever Australian Journal of Chemistry, 1982 , vol. 35, # 11 p. 2237 - 2245

~37%

(3 4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYL- Structure

(3 4-DIHYDRO-1-...

CAS#:38858-72-9

Detail
Literature: Shimizu, Sumio; Ogata, Masaru Journal of Organic Chemistry, 1986 , vol. 51, # 20 p. 3897 - 3900

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles1

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Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers.

Chem. Commun. (Camb.) (47) , 5049-51, (2007)

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone sub...

 Synonyms

(1,2-dihydronaphthalen-4-yloxy)trimethylsilane
(3,4-dihydronaphthalen-1-yloxy)trimethylsilane
(3,4-dihydro-1-naphthalenyloxy)(trimethyl)silane
3,4-Dihydro-1-(trimethylsilyloxy)naphthalene
(3,4-Dihydro-1-naphthyloxy)trimethylsilane
MFCD03093969
3,4-dihydronaphthalen-1(2H)-one trimethylsilyl enol ether