3,5-Bis(trifluoromethyl)benzene-1-sulfonyl chloride

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Names

[ CAS No. ]:
39234-86-1

[ Name ]:
3,5-Bis(trifluoromethyl)benzene-1-sulfonyl chloride

[Synonym ]:
3,5-bis(trifluoromethyl)benzene sulfonyl chloride
EINECS 254-371-0
3,5-Bis(trifluoromethyl)benzene-1-sulfonyl chloride
MFCD00014725
WSGR CXFFF EXFFF
Benzenesulfonyl chloride, 3,5-bis(trifluoromethyl)-
3,5-(bistrifluoromethyl)phenylsulfonyl chloride
3,5-Bis(trifluoromethyl)benzenesulphonyl chloride
3,5-di(trifluoromethyl)benzenesulfonyl chloride
3,5-Di(trifluoromethyl)benzene-1-sulfonyl chloride
3,5-Bis(trifluoromethyl)benzenesulfonyl chloride

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
248.3±40.0 °C at 760 mmHg

[ Melting Point ]:
34-38 °C(lit.)

[ Molecular Formula ]:
C8H3ClF6O2S

[ Molecular Weight ]:
312.617

[ Flash Point ]:
104.0±27.3 °C

[ Exact Mass ]:
311.944641

[ PSA ]:
42.52000

[ LogP ]:
4.07

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.435

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3,5-Di(trifluoromethyl)aniline

DownStream

  • 1-[3,5-bis(trifluoromethyl)phenyl]sulfonyl-5-ethoxypyrrolidin-2-one
  • 3,5-Bis(trifluoromethyl)thiophenol
  • 3,5-bis(trifluoromethyl)benzenesulfonamide

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

New library of aminosulfonyl-tagged Hoveyda-Grubbs type complexes: Synthesis, kinetic studies and activity in olefin metathesis transformations.

Beilstein J. Org. Chem. 6 , 1159-66, (2010)

Seven novel Hoveyda-Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda's precatalyst. A selection of these catalys...

Highly enantioselective catalytic thiolysis of prochiral cyclic dicarboxylic anhydrides utilizing a bifunctional chiral sulfonamide.

Angew. Chem. Int. Ed. Engl. 44(36) , 5838-41, (2005)

Versatile chiral reagent for the highly enantioselective synthesis of either anti or syn ester aldols. Corey EJ and Kim SS.

J. Am. Chem. Soc. 112(12) , 4976-4977, (1990)


More Articles

Related Compounds

  • Tert-butyl 4-amino-2-oxabicyclo[2.1.1]hexane-1-carboxylate
  • 6-{[(Benzyloxy)carbonyl]amino}-2-(ethylsulfanyl)pyrimidine-4-carboxylic acid
  • 8-{[(9H-fluoren-9-yl)methoxy]carbonyl}-2,2-dioxo-2lambda6-thia-8-azaspiro[4.5]decane-4-carboxylic acid
  • 2-{[(Benzyloxy)carbonyl]amino}-4-(dimethylphosphoryl)benzoic acid
  • 1-({[(Benzyloxy)carbonyl]amino}methyl)-3-(trifluoromethyl)-2-oxabicyclo[2.1.1]hexane-4-carboxylic acid
  • 2-{[4-({[(Benzyloxy)carbonyl]amino}methyl)piperidin-1-yl]sulfonyl}acetic acid
  • 5-{[(benzyloxy)carbonyl]amino}-1-(2-methylphenyl)-1H-imidazole-4-carboxylic acid
  • 3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethoxy]-2-methylbenzoic acid
  • ethyl (3R)-3-amino-3-(2-fluoro-4-methylphenyl)propanoate
  • 2-[6-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-5,6,7,8-tetrahydronaphthalen-2-yl]acetic acid
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