Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)-

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Names

[ CAS No. ]:
3975-77-7

[ Name ]:
Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)-

[Synonym ]:
2-bromo-1,3,5-tritert-butylbenzene
MFCD00191861

Chemical & Physical Properties

[ Density]:
1.064g/cm3

[ Boiling Point ]:
299.7ºC at 760mmHg

[ Melting Point ]:
168-173ºC(lit.)

[ Molecular Formula ]:
C18H29Br

[ Molecular Weight ]:
325.32700

[ Flash Point ]:
123.7ºC

[ Exact Mass ]:
324.14500

[ LogP ]:
6.34160

[ Index of Refraction ]:
1.494

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Precursor & DownStream

Precursor

  • 1,3,5-Tri-tert-butylbenzene
  • tris-(tert-butyl)benzene
  • lithium,1,3,5-tritert-butylbenzene-6-ide
  • Bromotrichlorosilane
  • (2,4,6-tritert-butylphenyl)-(2,4,6-tritert-butylphenyl)phosphanylidenephosphane
  • 2,4,6-TRI-TERT-BUTYLANILINE

DownStream

  • 1,3,5-tritert-butyl-2-[(2,4,6-tritert-butylphenyl)disulfanyl]benzene
  • 1,3,5-Tri-tert-butylbenzene
  • tri-n-butyltin bromide
  • 2,4,6-tritert-butylbenzenesulfonyl chloride
  • lithium,1,3,5-tritert-butylbenzene-6-ide
  • 1,3,5-tritert-butyl-2-iodobenzene
  • bis(2,4,6-tris(1,1-dimethylethyl)phenyl)phosphinic chloride
  • N-butyl-1-(2,4,6-tritert-butylphenyl)methanimine
  • 2,4,6-Tri-tert-butylbenzoic acid

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.

Org. Lett. 14(1) , 170-3, (2012)

A new bulky biarylphosphine ligand (L8) has been developed that allows the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions than previously possible....

Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

Angew. Chem. Int. Ed. Engl. 50(37) , 8647-51, (2011)

Rationalizing oligomerization in dimethylindium(III) chalcogenolates (Me2InER') (E = O, S, Se): a structural and computational study.

Dalton Trans. 39(16) , 3833-41, (2010)

The effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates (Me(2)InER') (E = O, S, Se) has been examined. The facile reaction of Me(3)In with a series of phenols, th...


More Articles


Related Compounds

  • 2-Bromo-1,3,5-triisopropylbenzene
  • 2-bromo-1,3,5-tri(pentan-3-yl)benzene
  • 2-bromo-1,3,5-tris(2,2-dimethylpropyl)-4-nitrobenzene
  • 2-bromo-5-tert-butyl-1,3-dimethylbenzene
  • 2-bromo-1-(bromomethyl)-3,5-ditert-butylbenzene
  • 1,3,5-Trineopentyl-2-bromobenzene
  • 2-[(3-Ethynylphenyl)amino]-1-(4-methylpiperazin-1-yl)ethan-1-one
  • 2-[(3-Ethynylphenyl)amino]ethanol
  • N-(3-Methylphenyl)-2-nitrobenzenemethanamine
  • 6-Methyl-2,3-dihydro-1,3-benzothiazole
  • 2,4-dimethyl-N-(2,2,2-trifluoroethyl)aniline
  • 2-[(6-Methoxypyridin-3-yl)amino]ethan-1-ol
  • N-[(5-chlorothiophen-2-yl)methyl]cyclohexanamine
  • N-(imidazo[1,2-a]pyridin-2-ylmethyl)cyclohexanamine
  • 2-[(2-methoxyethyl)amino]-N,N-dimethylacetamide
  • [(5-Chlorothiophen-2-yl)methyl](2-methylpropyl)amine
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