Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)-

Names

[ CAS No. ]:
3975-77-7

[ Name ]:
Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)-

[Synonym ]:
2-bromo-1,3,5-tritert-butylbenzene
MFCD00191861

Chemical & Physical Properties

[ Density]:
1.064g/cm3

[ Boiling Point ]:
299.7ºC at 760mmHg

[ Melting Point ]:
168-173ºC(lit.)

[ Molecular Formula ]:
C₁₈H₂₉Br

[ Molecular Weight ]:
325.32700

[ Flash Point ]:
123.7ºC

[ Exact Mass ]:
324.14500

[ LogP ]:
6.34160

[ Index of Refraction ]:
1.494

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,3,5-Tri-tert-butylbenzene
tris-(tert-butyl)benzene
lithium,1,3,5-tritert-butylbenzene-6-ide
Bromotrichlorosilane
(2,4,6-tritert-butylphenyl)-(2,4,6-tritert-butylphenyl)phosphanylidenephosphane
2,4,6-TRI-TERT-BUTYLANILINE

DownStream

1,3,5-tritert-butyl-2-[(2,4,6-tritert-butylphenyl)disulfanyl]benzene
1,3,5-Tri-tert-butylbenzene
tri-n-butyltin bromide
2,4,6-tritert-butylbenzenesulfonyl chloride
lithium,1,3,5-tritert-butylbenzene-6-ide
1,3,5-tritert-butyl-2-iodobenzene
bis(2,4,6-tris(1,1-dimethylethyl)phenyl)phosphinic chloride
N-butyl-1-(2,4,6-tritert-butylphenyl)methanimine
2,4,6-Tri-tert-butylbenzoic acid

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.

Org. Lett. 14(1) , 170-3, (2012)

A new bulky biarylphosphine ligand (L8) has been developed that allows the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions than previously possible....

Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

Angew. Chem. Int. Ed. Engl. 50(37) , 8647-51, (2011)

Rationalizing oligomerization in dimethylindium(III) chalcogenolates (Me2InER') (E = O, S, Se): a structural and computational study.

Dalton Trans. 39(16) , 3833-41, (2010)

The effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates (Me(2)InER') (E = O, S, Se) has been examined. The facile reaction of Me(3)In with a series of phenols, th...

2-Bromo-1,3,5-triisopropylbenzene
2-bromo-1,3,5-tri(pentan-3-yl)benzene
2-bromo-1,3,5-tris(2,2-dimethylpropyl)-4-nitrobenzene
2-bromo-5-tert-butyl-1,3-dimethylbenzene
2-bromo-1-(bromomethyl)-3,5-ditert-butylbenzene
1,3,5-Trineopentyl-2-bromobenzene
3-[(3R,4R)-1-(2-Aminoethyl)-3,4-dimethyl-4-piperidinyl]phenol
N-[(2-Chlorophenyl)methyl]-3-methyl-5-(morpholine-4-sulfonyl)-1-benzofuran-2-carboxamide
2-Fluoro-4-methoxy-I(2)-methylbenzenepropanenitrile
benzyl N-[1-(4-hydroxyphenyl)butan-2-yl]carbamate
1,1-Dimethyl-2,8-dioxasilocane
N-methyl N-(4-(methylsulfonylamino)phenylethyl) 2-(4-aminophenoxy)ethylamine
(S,E)-4-Amino-3-methylpent-2-enoic acid
2-ethoxy-N-[3-(1H-imidazol-1-yl)propyl]-4,5-dimethylbenzenesulfonamide
[(4-Bromonaphthyl)sulfonyl](3-imidazolylpropyl)amine
D-2-(Aminomethyl)-5,5-dimethyl-4-thiazolidinecarboxylic Acid

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