Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)-

Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)- Structure
Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)- structure
Common Name Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)-
CAS Number 3975-77-7 Molecular Weight 325.32700
Density 1.064g/cm3 Boiling Point 299.7ºC at 760mmHg
Molecular Formula C18H29Br Melting Point 168-173ºC(lit.)
MSDS Chinese USA Flash Point 123.7ºC
Symbol GHS07
GHS07
Signal Word Warning

A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.

Org. Lett. 14(1) , 170-3, (2012)

A new bulky biarylphosphine ligand (L8) has been developed that allows the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions than previously possible. A direct correlation between the size of the ligand substi...

Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

Angew. Chem. Int. Ed. Engl. 50(37) , 8647-51, (2011)

Rationalizing oligomerization in dimethylindium(III) chalcogenolates (Me2InER') (E = O, S, Se): a structural and computational study.

Dalton Trans. 39(16) , 3833-41, (2010)

The effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates (Me(2)InER') (E = O, S, Se) has been examined. The facile reaction of Me(3)In with a series of phenols, thiophenols and selenophenols afforded the compounds [Me(2)In...

The first Cu-and amine-free Sonogashira-type cross-coupling in the C-6-alkynylation of protected 2'-deoxyadenosine. Ngassa FN, et al.

Tetrahedron 65(21) , 4085-4091, (2009)