2-Bromobenzamide

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Names

[ CAS No. ]:
4001-73-4

[ Name ]:
2-Bromobenzamide

[Synonym ]:
EINECS 223-650-9
MFCD00007969
ZVR BE
o-Bromobenzamide
Benzamide, 2-bromo-
2-Bromobenzamide

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
298.0±23.0 °C at 760 mmHg

[ Melting Point ]:
160-162 °C(lit.)

[ Molecular Formula ]:
C7H6BrNO

[ Molecular Weight ]:
200.033

[ Flash Point ]:
134.0±22.6 °C

[ Exact Mass ]:
198.963272

[ PSA ]:
43.09000

[ LogP ]:
0.73

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.606

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Bromobenzonitrile
  • 2-Bromobenzaldoxime
  • Methyl 2-bromobenzoate
  • 2-Bromobenzaldehyde
  • Bromobenzene
  • 2-Bromostyrene
  • 1-(2-BROMOETHYL)PYRROLE
  • 2-Bromobenzoyl chloride
  • 2-Bromobenzoic acid

DownStream

  • 4-Quinazolinone
  • 1-Hydroxyisoquinoline
  • 2-Bromobenzonitrile
  • 5-(2-Bromophenyl)-1H-tetrazole
  • 2-Bromo-N-methylaniline
  • 2-Bromophenacyl bromide
  • 2-ethylquinazolin-4-ol
  • 1-(2-BROMOETHYL)PYRROLE
  • 2-phenylquinazolin-4-ol

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Organometallic Palladium Complexes with a Water-Soluble Iminophosphorane Ligand as Potential Anticancer Agents.

Organometallics 31(16) , 5772-5781, (2012)

The synthesis and characterization of a new water-soluble iminophosphorane ligand TPA=N-C(O)-2BrC(6)H(4) (C,N-IM; TPA = 1,3,5-triaza-7-phosphaadamantane) 1 is reported. Oxidative addition of 1 to Pd(2...

Palladium-catalyzed annulation of arynes by o-halobenzamides: synthesis of phenanthridinones.

J. Org. Chem. 77(19) , 8648-56, (2012)

The palladium-catalyzed annulation of arynes by substituted o-halobenzamides produces N-substituted phenanthridinones in good yields. This methodology provides this important heterocyclic ring system ...

Microwave assisted copper-free Sonogashira coupling/5-exo-dig cycloisomerization domino reaction: access to 3-(phenylmethylene) isoindolin-1-ones and related heterocycles. Hellal M and Cuny GD.

Tetrahedron Lett. 52(42) , 5508-11, (2011)


More Articles

Related Compounds

  • N-Butyl 2-bromobenzamide
  • N-allyl 2-bromobenzamide
  • 5-Amino-2-bromobenzamide
  • N-ethyl-2-bromobenzamide
  • N-methyl-2-bromobenzamide
  • N-Propyl 2-bromobenzamide
  • [(2-Bromo-5-chloro-4-methylphenyl)sulfonyl](1-ethyl-2-hydroxyethyl)amine
  • [(4-Butoxy-3-methylphenyl)sulfonyl](1-ethyl-2-hydroxyethyl)amine
  • [(4-Ethoxy-2,3-dimethylphenyl)sulfonyl](3-hydroxypropyl)amine
  • [(4,5-Dimethyl-2-propoxyphenyl)sulfonyl](3-hydroxypropyl)amine
  • [(5-Chloro-4-methyl-2-propoxyphenyl)sulfonyl](3-hydroxypropyl)amine
  • {[4-Bromo-5-methyl-2-(methylethyl)phenyl]sulfonyl}(2-hydroxypropyl)amine
  • [(4-Bromo-2,5-dichlorophenyl)sulfonyl](2-hydroxypropyl)amine
  • [(4,5-Dimethyl-2-pentyloxyphenyl)sulfonyl](3-hydroxypropyl)amine
  • [(5-Chloro-4-methyl-2-pentyloxyphenyl)sulfonyl](3-hydroxypropyl)amine
  • [(4-Chloro-3-propoxyphenyl)sulfonyl](3-hydroxypropyl)amine
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