2-Bromobenzamide

2-Bromobenzamide Structure
2-Bromobenzamide structure
Common Name 2-Bromobenzamide
CAS Number 4001-73-4 Molecular Weight 200.033
Density 1.6±0.1 g/cm3 Boiling Point 298.0±23.0 °C at 760 mmHg
Molecular Formula C7H6BrNO Melting Point 160-162 °C(lit.)
MSDS USA Flash Point 134.0±22.6 °C
Symbol GHS07
GHS07
Signal Word Warning

Organometallic Palladium Complexes with a Water-Soluble Iminophosphorane Ligand as Potential Anticancer Agents.

Organometallics 31(16) , 5772-5781, (2012)

The synthesis and characterization of a new water-soluble iminophosphorane ligand TPA=N-C(O)-2BrC(6)H(4) (C,N-IM; TPA = 1,3,5-triaza-7-phosphaadamantane) 1 is reported. Oxidative addition of 1 to Pd(2)(dba)(3) affords the orthopalladated dimer [Pd(-Br){C(6)H(...

Palladium-catalyzed annulation of arynes by o-halobenzamides: synthesis of phenanthridinones.

J. Org. Chem. 77(19) , 8648-56, (2012)

The palladium-catalyzed annulation of arynes by substituted o-halobenzamides produces N-substituted phenanthridinones in good yields. This methodology provides this important heterocyclic ring system in a single step by simultaneous C-C and C-N bond formation...

Microwave assisted copper-free Sonogashira coupling/5-exo-dig cycloisomerization domino reaction: access to 3-(phenylmethylene) isoindolin-1-ones and related heterocycles. Hellal M and Cuny GD.

Tetrahedron Lett. 52(42) , 5508-11, (2011)