ETHYL CHLOROFLUOROACETATE

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Names

[ CAS No. ]:
401-56-9

[ Name ]:
ETHYL CHLOROFLUOROACETATE

[Synonym ]:
Chlorofluoroacetic Acid Ethyl Ester
EINECS 206-930-5
Ethyl chlorofluoroacetate
MFCD00039333
ethyl 2-chloro-2-fluoroacetate

Chemical & Physical Properties

[ Density]:
1.212 g/mL at 25 °C(lit.)

[ Boiling Point ]:
133 °C(lit.)

[ Molecular Formula ]:
C4H6ClFO2

[ Molecular Weight ]:
140.54100

[ Flash Point ]:
125 °F

[ Exact Mass ]:
140.00400

[ PSA ]:
26.30000

[ LogP ]:
1.08390

[ Vapour Pressure ]:
10.4mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.396(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2915900090

Precursor & DownStream

Precursor

  • 2-Chloro-1,1,2-trifluoroethyl ethyl ether
  • chloro-fluoro-orthoacetic acid triethyl ester
  • Ethyl fluoroacetate
  • EDA
  • Ethanol
  • CHLOROFLUOROACETYL FLUORIDE
  • Chlorofluoroacetyl chloride

DownStream

  • ETHYL FLUORO(PHENYLTHIO)ACETATE
  • Chlorofluoroacetyl chloride
  • Acetic acid,2-chloro-2-fluoro-
  • Ethyl iodofluoroacetate
  • ethyl 2-fluoro-2-phenylselanylacetate
  • Ethyl (diethoxyphosphoryl)(fluoro)acetate
  • 2-chloro-2-fluoroethanol
  • SODIUM CHLOROFLUOROACETATE

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Ethyl alpha-fluoro silyl enol ether: stereoselective synthesis and its aldol reaction with aldehydes and ketones.

J. Org. Chem. 67(10) , 3231-4, (2002)

Ethyl alpha-fluoro silyl enol ether is stereoselectively synthesized in high yield from inexpensive chlorofluoroacetate and Mg (or Zn) in DMF (or HMPA). Lewis acid promoted aldol reaction of this enol...

The preparation of some derivatives of chlorofluoroacetic acid. Young JA and Tarrant P.

J. Am. Chem. Soc. 71(1) , 3278-3285, (1949)

One-step method for converting esters to acyl chlorides. Middleton WJ.

J. Org. Chem. 44(13) , 2291-2292, (1979)


More Articles

Related Compounds

  • ethyl 8-(4-fluorophenyl)-8-oxooctanoate
  • ETHYL 4-(3,4-DIMETHYLPHENYL)-4-OXOBUTYRATE
  • ethyl 3-(3-nitrophenyl)-4-oxopent-2-enoate
  • ETHYL 8-(1-NAPHTHYL)-8-OXOOCTANOATE
  • ETHYL 2-((TERT-BUTOXYCARBONYL)AMINO)THIAZOLE-5-CARBOXYLATE
  • ETHYL MORPHOLINE-2-CARBOXYLATE HYDROCHLORIDE
  • N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)tetrahydro-2H-pyran-4-carboxamide
  • N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)nicotinamide
  • N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)-2-(thiophen-2-yl)acetamide
  • (E)-3-(2,5-difluorophenyl)-N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)acrylamide
  • 2-(2,4-dichlorophenoxy)-N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)propanamide
  • 2-phenoxy-N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)propanamide
  • 2-(benzylthio)-N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)acetamide
  • 3-phenyl-N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)propanamide
  • N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)-1-naphthamide
  • 4-ethyl-2,3-dioxo-N-(2-(4-phenyl-1H-pyrazol-1-yl)ethyl)piperazine-1-carboxamide
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