ETHYL CHLOROFLUOROACETATE

ETHYL CHLOROFLUOROACETATE Structure
ETHYL CHLOROFLUOROACETATE structure
Common Name ETHYL CHLOROFLUOROACETATE
CAS Number 401-56-9 Molecular Weight 140.54100
Density 1.212 g/mL at 25 °C(lit.) Boiling Point 133 °C(lit.)
Molecular Formula C4H6ClFO2 Melting Point N/A
MSDS Chinese Flash Point 125 °F
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

Ethyl alpha-fluoro silyl enol ether: stereoselective synthesis and its aldol reaction with aldehydes and ketones.

J. Org. Chem. 67(10) , 3231-4, (2002)

Ethyl alpha-fluoro silyl enol ether is stereoselectively synthesized in high yield from inexpensive chlorofluoroacetate and Mg (or Zn) in DMF (or HMPA). Lewis acid promoted aldol reaction of this enol ether with aldehydes and ketones gives alpha-fluoro-beta-h...

The preparation of some derivatives of chlorofluoroacetic acid. Young JA and Tarrant P.

J. Am. Chem. Soc. 71(1) , 3278-3285, (1949)

One-step method for converting esters to acyl chlorides. Middleton WJ.

J. Org. Chem. 44(13) , 2291-2292, (1979)