m-iodobenzotrifluoride

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Names

[ CAS No. ]:
401-81-0

[ Name ]:
m-iodobenzotrifluoride

[Synonym ]:
3-(trifluoromethyl)iodobenzene
α,α,α-Trifluoro-m-iodotoluene
3-Iodo-α,α,α-trifluorotoluene
m-(Trifluoromethyl)iodobenzene
Benzene, 1-iodo-3- (trifluoromethyl)-
m-iodobenzotrifluoride
Benzene, 1-iodo-3-(trifluoromethyl)-
MFCD00001049
1-Iodo-3-(trifluoromethyl)benzene
Toluene, α,α,α-trifluoro-m-iodo-
3-trifluoromethyl-iodobenzene
EINECS 206-934-7

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
183.7±0.0 °C at 760 mmHg

[ Melting Point ]:
-8 °C

[ Molecular Formula ]:
C7H4F3I

[ Molecular Weight ]:
272.006

[ Flash Point ]:
70.0±0.0 °C

[ Exact Mass ]:
271.930969

[ LogP ]:
4.02

[ Vapour Pressure ]:
1.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.521

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S27-S36/37/39-S45-S37/39

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-(Trifluoromethyl)phenylboronic acid
  • Benzotrifluoride
  • 3-Bromobenzotrifluoride
  • Iodobenzene
  • (Trifluoromethyl)trimethylsilane
  • 3-(Trifluoromethyl)aniline
  • Sodium benzenolate
  • m-(trifluoromethyl)diphenyliodonium iodide
  • trifluoro(trifluoromethyltellanyl)methane

DownStream

  • 1-(4-Bromophenoxy)-3-(trifluoromethyl)benzene
  • N,N-diphenyl-3-(trifluoromethyl)aniline
  • Triphenylamine
  • Ethyl-3-iodobenzoate
  • 4,4'-Dinitro-3,3'-bis(trifluoromethyl)-1,1'-biphenyl
  • 3-(Trifluoromethyl)anisole
  • 4,4,5,5-TETRAMETHYL-2-(3-(TRIFLUOROMETHYL)PHENYL)-1,3,2-DIOXABOROLANE
  • 3-(Trifluoromethyl)benzoic acid
  • 3-(Trifluoromethyl)benzaldehyde
  • 3′-(Trifluoromethyl)acetophenone

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Efficient solvent- and metal-free Sonogashira protocol catalysed by 1,4-diazabicyclo(2.2.2) octane (DABCO).

Org. Biomol. Chem. 7(8) , 1627-32, (2009)

An efficient metal-free Sonogashira coupling protocol catalysed by DABCO is reported, where very good conversions and selectivities to the cross-coupling product were obtained under mild reaction cond...

New synthesis of zinc tetrakis(arylethynyl)porphyrins and substituent effects on their redox chemistry.

Dalton Trans. (14) , 1433-9, (2007)

Sonogashira coupling of zinc 5,10,15,20-tetraethynylporphyrin with various phenyl iodides under mild conditions afforded good yields of the corresponding zinc porphyrins. This method is applicable to ...


More Articles

Related Compounds

  • 3-(4,6-diamino-1,3,5-triazin-2-yl)benzonitrile (en)Benzonitrile, 3-(4,6-diamino-1,3,5-triazin-2-yl)- (en)
  • m-(trifluoromethyl)diphenyliodonium iodide
  • m-isopropylphenethyl alcohol
  • m-PEG8-Tos
  • m-(1-Benzyl-3-propyl-3-pyrrolidinyl)phenol
  • m-methoxydiphenyliodonium iodide