m-iodobenzotrifluoride

m-iodobenzotrifluoride Structure
m-iodobenzotrifluoride structure
Common Name m-iodobenzotrifluoride
CAS Number 401-81-0 Molecular Weight 272.006
Density 1.9±0.1 g/cm3 Boiling Point 183.7±0.0 °C at 760 mmHg
Molecular Formula C7H4F3I Melting Point -8 °C
MSDS USA Flash Point 70.0±0.0 °C
Symbol GHS05
GHS05
Signal Word Danger

Efficient solvent- and metal-free Sonogashira protocol catalysed by 1,4-diazabicyclo(2.2.2) octane (DABCO).

Org. Biomol. Chem. 7(8) , 1627-32, (2009)

An efficient metal-free Sonogashira coupling protocol catalysed by DABCO is reported, where very good conversions and selectivities to the cross-coupling product were obtained under mild reaction conditions. The reported solvent-, phosphane- and metal-free pr...

New synthesis of zinc tetrakis(arylethynyl)porphyrins and substituent effects on their redox chemistry.

Dalton Trans. (14) , 1433-9, (2007)

Sonogashira coupling of zinc 5,10,15,20-tetraethynylporphyrin with various phenyl iodides under mild conditions afforded good yields of the corresponding zinc porphyrins. This method is applicable to a variety of aryl iodides including meso-substituted iodopo...