((4s,5s)-(+)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate
Names
[ CAS No. ]:
405235-55-4
[ Name ]:
((4s,5s)-(+)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate
[Synonym ]:
((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)tetrakis-(3,5-bis(trifluoromethyl)phenyl
((4S,5S)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethy
((4S,5S)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)tetrakis(3,5-bis(trifluoromethyl)phenylborate,min.
((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate,min. (S,S)-[COD]Ir[Ph2PT
Chemical & Physical Properties
[ Melting Point ]:
112-113ºC
[ Molecular Formula ]:
C77H58BF24IrNO2P
[ Molecular Weight ]:
1719.25000
[ Exact Mass ]:
1719.35000
[ PSA ]:
44.41000
[ LogP ]:
20.53680
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Safety Phrases ]:
22-24/25
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
28439000
Articles
Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)
Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.
Adv. Synth. Catal. 344 , 40-44, (2002)