Trifluoroacetic anhydride

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Names

[ CAS No. ]:
407-25-0

[ Name ]:
Trifluoroacetic anhydride

[Synonym ]:
trifluoro acetic anhydride
trifluoroacetic
TRIFLUORACETIC ANHYDRIDE
Trifluoroacetyl anhydride
Perfluoracetic anhydride
trifluoroacetylanhydride
perfluoroaceticanhydride
MFCD00000416
Trifluoromethanesulfonic acid
2,2,2-trifluoroacetic anhydride
Trifluoroacetic Anhydride (TFAA)
hexafluoroacetic anhydride
Trifluoroacetic acid anhydride
EINECS 206-982-9
bis-trifluoroacetic anhydride
TFAA
Trifluoroacetic anhy
Perfluoroacetic anhydride
Trifluoroacetic anhydride
RIFLUOROACETIC ANHYDRIDE
TRIFLUOROACETO ANHYDRIDE
TIFLUOROACETIC ANHYDRIDE

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
39.5±0.0 °C at 760 mmHg

[ Melting Point ]:
-63.5 °C

[ Molecular Formula ]:
C4F6O3

[ Molecular Weight ]:
210.031

[ Flash Point ]:
-26.1±20.8 °C

[ Exact Mass ]:
209.975159

[ PSA ]:
43.37000

[ LogP ]:
2.56

[ Vapour Pressure ]:
438.6±0.0 mmHg at 25°C

[ Index of Refraction ]:
1.291

[ Stability ]:
Stable, but moisture sensitive. Reacts with water to liberate hydrogen (flammable!). Incompatible with water, strong oxidizing agents.

[ Water Solubility ]:
Hydrolysis

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AJ9800000
CHEMICAL NAME :
Acetic acid, trifluoro-, anhydride
CAS REGISTRY NUMBER :
407-25-0
BEILSTEIN REFERENCE NO. :
0746197
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-F6-O3
MOLECULAR WEIGHT :
210.04
WISWESSER LINE NOTATION :
FXFFVOVXFFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,575,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,575,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4633 No. of Facilities: 147 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 5451 (estimated) No. of Female Employees: 1249 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H332

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R14;R20;R35;R52/53

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S61-S9-S8-S28A-S27

[ RIDADR ]:
UN 3265 8/PG 1

[ WGK Germany ]:
2

[ RTECS ]:
AJ9800000

[ Packaging Group ]:
I

[ Hazard Class ]:
8

[ HS Code ]:
29159080

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • diiodo(trifluoromethyl)phosphane
  • silver trifluoroacetate-
  • 2,2,2-Trifluoroethyl trifluoroacetate
  • trifluoroacetic acid
  • (pentafluoro-l6-tellanyl)sulfurimidous dichloride
  • Oxytocin acetate salt
  • Ethyl trifluoroacetate
  • Nitrogen

DownStream

  • 1H-Pyrrole, 2,5-dihydro-1-(trifluoroacetyl)- (9CI)
  • 5-METHOXYNICOTINALDEHYDE OXIME
  • 2,2,2-trifluoro-N-propylacetamide
  • 6-methyl-2-(trifluoromethyl)-3,1-benzoxazin-4-one
  • 4-Acetylphenyl Trifluoromethanesulfonate
  • 3,5-dibromotyrosine trifluoroacetamide methyl ester
  • Ethanone, 1-(3,4-dihydro-2H-pyran-5-yl)-2,2,2-trifluoro- (9CI)
  • 2,2,2-trifluoro-N-[2-(1-methylindol-3-yl)ethyl]acetamide
  • (2-methoxy-2-oxoethyl) 2,2,2-trifluoroacetate
  • N-[2-(5,6-diphenyl-1,2,4-triazin-3-yl)phenyl]-2,2,2-trifluoroacetamide

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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Related Compounds

  • trifluoroacetic anhydride
  • trifluoroacetic anhydride
  • benzoic trifluoroacetic anhydride
  • acrylic-trifluoroacetic anhydride
  • Fluorosulfuric trifluoroacetic anhydride
  • methanesulphonyltrifluoroacetic anhydride
  • Methyl 4-amino-3-(2-hydroxy-5-methylphenyl)butanoate
  • Methyl 3-(1-amino-2-methylpropan-2-yl)-4-methoxybenzoate
  • (2,5,5-Trimethyl-1,4-dioxan-2-yl)methanesulfonyl fluoride
  • Methyl6-aminobicyclo[3.1.0]hexane-6-carboxylatehydrochloride
  • 4-[(2-{[(Benzyloxy)carbonyl]amino}propyl)carbamoyl]butanoic acid
  • Methyl 6-aminobicyclo[4.1.1]octane-1-carboxylate
  • 5-bromo-1H,2H,3H-pyrrolo[2,3-b]pyridine-1-sulfonyl chloride
  • 4-(Fluorosulfonyl)-3-formylbenzoic acid
  • (2R,4R)-2-(bromomethyl)-4-methoxypyrrolidine
  • Tert-butyl 3-{[(tert-butoxy)carbonyl](methyl)amino}-3-(hydroxymethyl)azetidine-1-carboxylate
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