4-methylbenzo[c]phenanthrene

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Names

[ CAS No. ]:
4076-40-8

[ Name ]:
4-methylbenzo[c]phenanthrene

[Synonym ]:
BENZO(c)PHENANTHRENE,4-METHYL
8-Methyl-3:4-benzphenanthrene
4-Methyl-3,4-benzophenanthrene
8-methyl-3,4-benzophenanthrene
4-methyl-benzo{c}phenanthrene
4-Methyl-benzo[c]phenanthren

Chemical & Physical Properties

[ Density]:
1.164g/cm3

[ Boiling Point ]:
449.4ºC at 760 mmHg

[ Molecular Formula ]:
C19H14

[ Molecular Weight ]:
242.31400

[ Flash Point ]:
217.8ºC

[ Exact Mass ]:
242.11000

[ LogP ]:
5.45460

[ Index of Refraction ]:
1.748

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DI9275000
CHEMICAL NAME :
Benzo(c)phenanthrene, 4-methyl-
CAS REGISTRY NUMBER :
4076-40-8
BEILSTEIN REFERENCE NO. :
2329428
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C19-H14
MOLECULAR WEIGHT :
242.33
WISWESSER LINE NOTATION :
L C6 B666J G1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
14 gm/kg/71W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors
REFERENCE :
PRLBA4 Proceedings of the Royal Society of London, Series B: Biological Sciences. (Royal Soc., 6 Carlton House Terrace, London SW1Y 5AG, UK) V.76- 1905- Volume(issue)/page/year: 129,439,1940
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1460 mg/kg/61W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application
REFERENCE :
PRLBA4 Proceedings of the Royal Society of London, Series B: Biological Sciences. (Royal Soc., 6 Carlton House Terrace, London SW1Y 5AG, UK) V.76- 1905- Volume(issue)/page/year: 129,439,1940
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4600 mg/kg/68W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors Skin and Appendages - tumors
REFERENCE :
PRLBA4 Proceedings of the Royal Society of London, Series B: Biological Sciences. (Royal Soc., 6 Carlton House Terrace, London SW1Y 5AG, UK) V.76- 1905- Volume(issue)/page/year: 129,439,1940

Safety Information

[ HS Code ]:
2902909090

Synthetic Route

Precursor & DownStream

Precursor

  • 4-methyl-5,6,7,8-tetrahydrobenzo[c]phenanthrene
  • 1,1-difluoro-2-(2-phenylethyl)-4-(2-methylphenyl)but-1-ene
  • o-xylene
  • o-xylyllithium
  • trans-2-(o-methyl-β-styryl)naphthalene
  • METHYLMAGNESIUM IODIDE
  • 11,12-dihydro-10H-benzo[c]phenanthren-9-one
  • 2-Naphthaldehyde
  • α-Bromo-o-xylene

DownStream

  • N-Phenyl-terephthalamidsaeure-methylester

Customs

[ HS Code ]: 2902909090

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%


Related Compounds

  • 4-methylbenzo[c]phenanthrene,2,4,7-trinitrofluoren-9-one
  • 4-methylbenzo[c]quinolizin-11-ium,chloride
  • 4-Methylbenzo[c]cinnoline
  • 4-bromo-2,5,7-trinitrofluoren-9-one,1-methylbenzo[c]phenanthrene
  • 2-methylbenzo[c]phenanthrene,2,4,7-trinitrofluoren-9-one
  • 3-methylbenzo[c]phenanthrene,2,4,7-trinitrofluoren-9-one