palladium(ii) trifluoroacetate

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Names

[ CAS No. ]:
42196-31-6

[ Name ]:
palladium(ii) trifluoroacetate

[Synonym ]:
palladium(2+),2,2,2-trifluoroacetate
Trifluoroacetic acid palladium(II) salt
Pd(TFA)2 (Trifluoroacetic acid palladium(II) salt
Palladium(2+) bis(trifluoroacetate)
Palladium(II) 2,2,2-trifluoroacetate
MFCD00013204
Acetic acid, 2,2,2-trifluoro-, palladium(2+) salt (2:1)
Palladium(II) trifluoroacetate

Chemical & Physical Properties

[ Boiling Point ]:
72.2ºCat 760 mmHg

[ Melting Point ]:
~220 °C

[ Molecular Formula ]:
[C2F3O2]2Pd+

[ Molecular Weight ]:
332.45

[ Exact Mass ]:
331.873566

[ PSA ]:
52.60000

[ LogP ]:
1.11240

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Articles

Synthesis of aryl ketones by palladium(II)-catalyzed decarboxylative addition of benzoic acids to nitriles.

Angew. Chem. Int. Ed. Engl. 49 , 7733, (2010)

The catalytic cross-coupling of unactivated arenes.

Science 316 , 1172, (2007)

The industrially important coupling of aromatic compounds has generally required differential prefunctionalization of the arene coupling partners with a halide and an electropositive group. Here we re...

Palladium-catalyzed 2-pyridylmethyl transfer from 2-(2-pyridyl)ethanol derivatives to organic halides by chelation-assisted cleavage of unstrained C(sp3 )--C(sp3) bonds.

Angew. Chem. Int. Ed. Engl. 46 , 2643, (2007)


More Articles


Related Compounds

  • Allylpalladium(II) trifluoroacetate
  • PALLADIUM(II) IODIDE
  • Palladium(II) Nitrate Hydrate
  • PALLADIUM(II),BIS(2-OXO-2H-1-BENZOPYRAN-3-YLAMMINE)DIIODO-,(Z)
  • PALLADIUM(II) 2,4-PENTANEDIONATE/ 99.95"
  • palladium(ii) bromide
  • 5-Chloropyrimido[5,4-e][1,2,4]triazine
  • 3-(1-Isopropyltriazol-4-yl)-5-(1-methylindol-5-yl)pyridin-2-amine
  • 3-(1-Isopropyl-1H-1,2,3-triazol-4-yl)-5-(4-(2-morpholinoethyl)phenyl)pyridin-2-amine
  • Ethyl 3-[4-(2-phenylethenyl)phenyl]-2-propenoate
  • (1'-Methoxy-9,9'-spirobi[xanthen]-1-yl)diphenylphosphine
  • 6-amino-4-phenyl-2(1H)-quinazolinone
  • 3-Amino-2-hydroxy-3-(4-hydroxyphenyl)propanoic acid
  • 7-(2-Anilinoethyl)-3-methyl-4,5-dihydropurine-2,6-dione
  • 1,3-Dimethyl-8-[(4-phenylpiperazin-1-yl)methyl]purin-3-ium-2,6-dione
  • 7-Benzyl-3-methyl-8-(3-methylpiperidin-1-yl)-4,5-dihydropurine-2,6-dione
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