palladium(ii) trifluoroacetate
palladium(ii) trifluoroacetate structure
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Common Name | palladium(ii) trifluoroacetate | ||
|---|---|---|---|---|
| CAS Number | 42196-31-6 | Molecular Weight | 332.45 | |
| Density | N/A | Boiling Point | 72.2ºCat 760 mmHg | |
| Molecular Formula | [C2F3O2]2Pd+ | Melting Point | ~220 °C | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Synthesis of aryl ketones by palladium(II)-catalyzed decarboxylative addition of benzoic acids to nitriles.
Angew. Chem. Int. Ed. Engl. 49 , 7733, (2010)
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The catalytic cross-coupling of unactivated arenes.
Science 316 , 1172, (2007) The industrially important coupling of aromatic compounds has generally required differential prefunctionalization of the arene coupling partners with a halide and an electropositive group. Here we report that palladium, in conjunction with a copper oxidant, ... |
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Palladium-catalyzed 2-pyridylmethyl transfer from 2-(2-pyridyl)ethanol derivatives to organic halides by chelation-assisted cleavage of unstrained C(sp3 )--C(sp3) bonds.
Angew. Chem. Int. Ed. Engl. 46 , 2643, (2007)
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Tetrahedron Lett. 25 , 4187, (1984)
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Development of a catalytic aromatic decarboxylation reaction.
Org. Lett. 9 , 2441, (2007) A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields. The method was useful with complex functionalized substrates containi... |
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Enantioselective Pd-catalyzed hydrogenation of fluorinated imines: facile access to chiral fluorinated amines.
Org. Lett. 12 , 5075, (2010) An enantioselective hydrogenation of simple fluorinated imines has been developed using Pd(OCOCF(3))(2)/(R)-Cl-MeO-BIPHEP as a catalyst, and up to 94% ee was achieved. This method provides an efficient route to enantioenriched fluorinated amines. |
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Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides.
Angew. Chem. Int. Ed. Engl. 49 , 5529, (2010)
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Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate.
J. Org. Chem. 73 , 8654, (2008) Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics. One of the major drawbacks of the homogeneous system is the tendenc... |
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Intermolecular methoxycarbonylation of terminal alkynes catalyzed by palladium(II) bis(oxazoline) complexes.
Angew. Chem. Int. Ed. Engl. 48 , 3326, (2009) Boxing clever: Direct conversion of a terminal alkyne group into a beta-methoxyacrylate is realized with the aid of the bis(oxazoline) ligand (box). Acetyl and ketal protecting groups, free hydroxy groups, and acid-sensitive glycosidic bonds are not affected ... |
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A general palladium-catalyzed sonogashira coupling of aryl and heteroaryl tosylates.
Chemistry 16 , 9986, (2010)
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