(|S|)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine

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Names

[ CAS No. ]:
443347-10-2

[ Name ]:
(|S|)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine

[Synonym ]:
MFCD04974235
(S)-Xylyl-P-Phos
(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE

Chemical & Physical Properties

[ Melting Point ]:
158-162ºC

[ Molecular Formula ]:
C46H50N2O4P2

[ Molecular Weight ]:
756.84800

[ Exact Mass ]:
756.32500

[ PSA ]:
89.88000

[ LogP ]:
8.16160

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Bromo-2,6-dimethoxypyridine
  • 3,5-dimethylphenylmagnesium bromide
  • Bis(3,5-dimethylphenyl)chlorophosphine
  • 4-(bis(3,5-dimethylphenyl)phosphanyl)-3-bromo-2,6-dimethoxypyridine
  • 4-bis(3,5-dimethylphenyl)phosphoryl-3-bromo-2,6-dimethoxypyridine

DownStream

Articles

P-Phos: a family of versatile and effective atropisomeric dipyridylphosphine ligands in asymmetric catalysis.

Acc. Chem. Res. 39 , 711, (2006)

This Account outlines our efforts in the design and synthesis of a family of highly effective atropisomeric dipyridylphosphine ligands (P-Phos and its variants) and in the development of their widespr...


More Articles

Related Compounds

  • 5-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-methylpentanamido]-3-methyl-1,2-thiazole-4-carboxylic acid
  • 4-(Propane-2-sulfonyl)thiophene-3-carbaldehyde
  • 1-{2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methoxypropanamido]ethyl}-1H-1,2,3-triazole-4-carboxylic acid
  • 3-[(4-bromo-2-fluoro-5-methylphenyl)carbamoyl]-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid
  • 2-{2-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanamido]phenyl}acetic acid
  • (4R)-3-[4-bromo-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)benzoyl]-1,3-thiazolidine-4-carboxylic acid
  • 2-[2-(Dimethylamino)-4-methoxy-1,3-thiazol-5-yl]butanoic acid
  • 3-({4-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]phenyl}formamido)-2-hydroxypropanoic acid
  • 3-{2-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)piperidin-1-yl]acetamido}-2-hydroxypropanoic acid
  • 1-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-2-methylbutanamido}cyclopentane-1-carboxylic acid
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