(|S|)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine

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Names

[ CAS No. ]:
443347-10-2

[ Name ]:
(|S|)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine

[Synonym ]:
MFCD04974235
(S)-Xylyl-P-Phos
(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE

Chemical & Physical Properties

[ Melting Point ]:
158-162ºC

[ Molecular Formula ]:
C46H50N2O4P2

[ Molecular Weight ]:
756.84800

[ Exact Mass ]:
756.32500

[ PSA ]:
89.88000

[ LogP ]:
8.16160

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Bromo-2,6-dimethoxypyridine
  • 3,5-dimethylphenylmagnesium bromide
  • Bis(3,5-dimethylphenyl)chlorophosphine
  • 4-(bis(3,5-dimethylphenyl)phosphanyl)-3-bromo-2,6-dimethoxypyridine
  • 4-bis(3,5-dimethylphenyl)phosphoryl-3-bromo-2,6-dimethoxypyridine

DownStream

Articles

P-Phos: a family of versatile and effective atropisomeric dipyridylphosphine ligands in asymmetric catalysis.

Acc. Chem. Res. 39 , 711, (2006)

This Account outlines our efforts in the design and synthesis of a family of highly effective atropisomeric dipyridylphosphine ligands (P-Phos and its variants) and in the development of their widespr...


More Articles

Related Compounds

  • 3-Chloro-5-cyclopropoxy-2-fluoropyridine
  • 2-Tert-butoxy-4-cyclopropoxy-6-methoxypyridine
  • N-(4-Aminocyclohexyl)-3-methylbut-2-enamide
  • 3-Cyclopropoxy-2-fluoro-5-(methylthio)pyridine
  • 5-Cyclopropoxy-4-(methylamino)nicotinic acid
  • 3-Cyclopropoxy-N,N-dimethyl-5-(methylthio)pyridin-2-amine
  • 4-Cyclopropoxy-2-methoxy-5-(methylthio)pyridine
  • 1-(3-((6-Amino-5-(4-phenoxyphenyl)pyrimidin-4-yl)amino)azetidin-1-yl)prop-2-en-1-one
  • Methyl 4-chloro-2-isobutoxybenzoate
  • (2-Cyclopropoxy-5-isopropylphenyl)(methyl)sulfane
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