(|S|)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine

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Names

[ Name ]:
(|S|)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine

[Synonym ]:
MFCD04974235
(S)-Xylyl-P-Phos
(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE

Chemical & Physical Properties

[ Melting Point ]:
158-162ºC

[ Molecular Formula ]:
C₄₆H₅₀N₂O₄P₂

[ Molecular Weight ]:
756.84800

[ Exact Mass ]:
756.32500

[ PSA ]:
89.88000

[ LogP ]:
8.16160

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3-Bromo-2,6-dimethoxypyridine
3,5-dimethylphenylmagnesium bromide
Bis(3,5-dimethylphenyl)chlorophosphine
4-(bis(3,5-dimethylphenyl)phosphanyl)-3-bromo-2,6-dimethoxypyridine
4-bis(3,5-dimethylphenyl)phosphoryl-3-bromo-2,6-dimethoxypyridine

DownStream

Articles

P-Phos: a family of versatile and effective atropisomeric dipyridylphosphine ligands in asymmetric catalysis.

Acc. Chem. Res. 39 , 711, (2006)

This Account outlines our efforts in the design and synthesis of a family of highly effective atropisomeric dipyridylphosphine ligands (P-Phos and its variants) and in the development of their widespr...

[3-(4-chlorophenyl)-1-methyl-1H-pyrazol-5-yl][4-(3-methoxyphenyl)piperazino]methanone
3-Amino-4-(3,4-dimethoxyphenyl)-1-(3-fluorophenyl)azetidin-2-one
2-(2-methoxyethyl)-N-[2-(5-methoxy-1H-indol-1-yl)ethyl]-1-oxo-1,2-dihydro-4-isoquinolinecarboxamide
3-Amino-1-(3-fluorophenyl)-4-(3-methoxyphenyl)azetidin-2-one
N-[2-oxo-2-(4H-1,2,4-triazol-3-ylamino)ethyl]pyrazine-2-carboxamide
3-Amino-4-(benzo[d][1,3]dioxol-5-yl)-1-(3-fluorophenyl)azetidin-2-one
[4-(4-chlorophenyl)-4-hydroxypiperidino](1-methyl-3-phenyl-1H-pyrazol-5-yl)methanone
3-Amino-4-(2-chlorophenyl)-1-(3-fluorophenyl)azetidin-2-one
N-[2-(cycloheptylamino)-2-oxoethyl]-2-pyrazinecarboxamide
3-Amino-4-(3-chlorophenyl)-1-(3-fluorophenyl)azetidin-2-one

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