Methyl 2-bromoacrylate

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Names

[ CAS No. ]:
4519-46-4

[ Name ]:
Methyl 2-bromoacrylate

[Synonym ]:
methyl 2-bromopropenoate
2-Brom-acrylsaeure-methylester
MFCD08276754
2-Propenoic acid,2-bromo-,methyl ester
2-Propenoic acid, 2-bromo-, methyl ester
Methyl 2-bromoacrylate
2-bromo-acrylic acid methyl ester
Methyl |A-bromoacrylate
Methyl-(2-brom-acrylat)
Methylalpha-bromoacrylate
monobromo methyl acrylate

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
139.7±13.0 °C at 760 mmHg

[ Molecular Formula ]:
C4H5BrO2

[ Molecular Weight ]:
164.985

[ Flash Point ]:
38.3±19.8 °C

[ Exact Mass ]:
163.947281

[ PSA ]:
26.30000

[ LogP ]:
1.11

[ Vapour Pressure ]:
6.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.471

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 1993 3/PG 3

[ HS Code ]:
2916190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • acrylic acid methyl ester
  • Methyl 2,3-dibromopropionate
  • exo-6-Bromo-5-carbomethoxy-1,6-diazabicyclo[3.1.0]hexane
  • 2-Brom-3-chlorpionsaeure-methylester
  • methyl 2,2-dibromo-2-(methylthio)acetate

DownStream

  • Dimethyl 1H-pyrazole-3,5-dicarboxylate
  • Fenipentol
  • 4-hydroxy-4-phenyl-but-2-ynoic acid methyl ester
  • Methyl 2-bromobut-2-enoate
  • trimethyl cyclopropane-1,1,2-tricarboxylate
  • methyl 2-bromo-3-methoxypropanoate
  • 1,1,2,2-Ethenetetracarboxylicacid, 1,1,2,2-tetramethyl ester
  • trimethyl 2-bromocyclopropane-1,1,2-tricarboxylate

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Copolymerizations of methyl α-bromoacrylate, 2-bromoethyl methacrylate and 2,3-dibromopropyl methacrylate with vinyltriacetoxysilane Rao VL and Babu GN

Eur. Polym. J. 26(2) , 227-231, (1990)

1,2,2-tribromocyclopropanecarboxylic acid and derivatives—Valuable intermediates for four carbon cyclopropane and cyclopropene synthons Al Dulayymi AR, et al.

Tetrahedron 52(10) , 3409-3424, (1996)

A Novel Synthesis of Methyl Acrylate-α-d and 1H Nuclear Magnetic Resonance Spectra of Its Alternating Copolymers. Yokota K, et al.

Polymer J. 12(3) , 177-181, (1980)


More Articles

Related Compounds

  • methyl 2-bromoacrylate
  • methyl 2-bromoacrylate
  • methyl 2-(3-oxobutyl)benzoate
  • methyl 2-[4-methyl-7-(2-oxopropoxy)-2-oxo-2H-3-chromenyl]acetate
  • methyl 2-[2-(2-methoxy-2-oxoethyl)phenyl]acetate
  • Methyl 2-(2-chlorophenyl)-2-(4,5-dihydrothieno[2,3-c]pyridin-6(7H)-yl)acetate
  • (3S,4S)-4-Phenylpyrrolidin-3-ol
  • (2S)-2-Methyl-4-nitrobutanoic acid
  • (3R)-3-amino-3-cyclohexylpropanamide
  • 7-Bromo-3-trityl-3H-benzooxazol-2-one
  • (1S,2S)-2-(cyclobutylamino)cyclohexan-1-ol
  • (R)-2-(Bromomethyl)-1,4-dioxane
  • (2S)-2,5,5-Trimethylhexan-1-amine
  • (2S)-2-Methyl-3-(oxan-4-yl)propan-1-amine
  • (2R)-2-Methyl-3-(oxan-4-yl)propan-1-amine
  • (2S)-3-Cyclopentyl-2-methylpropan-1-amine
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