Methyl 2-bromoacrylate

Modify Date: 2024-01-11 22:47:10

Methyl 2-bromoacrylate Structure
Methyl 2-bromoacrylate structure
Common Name Methyl 2-bromoacrylate
CAS Number 4519-46-4 Molecular Weight 164.985
Density 1.6±0.1 g/cm3 Boiling Point 139.7±13.0 °C at 760 mmHg
Molecular Formula C4H5BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 38.3±19.8 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name methyl 2-bromoprop-2-enoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 139.7±13.0 °C at 760 mmHg
Molecular Formula C4H5BrO2
Molecular Weight 164.985
Flash Point 38.3±19.8 °C
Exact Mass 163.947281
PSA 26.30000
LogP 1.11
Vapour Pressure 6.4±0.3 mmHg at 25°C
Index of Refraction 1.471
Storage condition -20°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases 26-36
RIDADR UN 1993 3/PG 3
HS Code 2916190090

 Synthetic Route

~86%

Methyl 2-bromoacrylate Structure

Methyl 2-bromoa...

CAS#:4519-46-4

Literature: Ye, Chengfeng; Shreeve, Jean'Ne M. Journal of Organic Chemistry, 2004 , vol. 69, # 24 p. 8561 - 8563

~88%

Methyl 2-bromoacrylate Structure

Methyl 2-bromoa...

CAS#:4519-46-4

Literature: Pace, Vittorio; Castoldi, Laura; Alcantara, Andres R.; Holzer, Wolfgang Green Chemistry, 2012 , vol. 14, # 7 p. 1859 - 1863

~%

Methyl 2-bromoacrylate Structure

Methyl 2-bromoa...

CAS#:4519-46-4

Literature: Shustov, G. V.; Denisenko, S. N.; Shibaev, A. Yu.; Puzanov, Yu. V.; Mal'donado, I. K. A. Romero; Kostyanovskii, R. G. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, # 10 p. 2123 - 2127 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 10 p. 2358 - 2362

~%

Methyl 2-bromoacrylate Structure

Methyl 2-bromoa...

CAS#:4519-46-4

Literature: Heasley,V.L. et al. Journal of Organic Chemistry, 1979 , vol. 44, p. 2608 - 2611

~%

Methyl 2-bromoacrylate Structure

Methyl 2-bromoa...

CAS#:4519-46-4

Literature: Pommelet, Jean-Claude; Nyns, Claire; Lahousse, Francis; Merenyi, Robert; Viehe, Heinz G. Angewandte Chemie, 1981 , vol. 93, # 6/7 p. 594 - 595

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles4

More Articles
Copolymerizations of methyl α-bromoacrylate, 2-bromoethyl methacrylate and 2,3-dibromopropyl methacrylate with vinyltriacetoxysilane Rao VL and Babu GN

Eur. Polym. J. 26(2) , 227-231, (1990)

1,2,2-tribromocyclopropanecarboxylic acid and derivatives—Valuable intermediates for four carbon cyclopropane and cyclopropene synthons Al Dulayymi AR, et al.

Tetrahedron 52(10) , 3409-3424, (1996)

A Novel Synthesis of Methyl Acrylate-α-d and 1H Nuclear Magnetic Resonance Spectra of Its Alternating Copolymers. Yokota K, et al.

Polymer J. 12(3) , 177-181, (1980)

 Synonyms

methyl 2-bromopropenoate
2-Brom-acrylsaeure-methylester
MFCD08276754
2-Propenoic acid,2-bromo-,methyl ester
2-Propenoic acid, 2-bromo-, methyl ester
Methyl 2-bromoacrylate
2-bromo-acrylic acid methyl ester
Methyl |A-bromoacrylate
Methyl-(2-brom-acrylat)
Methylalpha-bromoacrylate
monobromo methyl acrylate