3-Bromo-4-chlorobenzotrifluoride

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Names

[ CAS No. ]:
454-78-4

[ Name ]:
3-Bromo-4-chlorobenzotrifluoride

[Synonym ]:
3-Bromo-4-chloro-α,α,α-trifluorotoluene
Benzene, 2-bromo-1-chloro-4-(trifluoromethyl)-
EINECS 207-226-0
2-Bromo-1-chloro-4-(trifluoromethyl)benzene
MFCD00018093
3-BroMo-4-chlorobenzotrifluoride

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
189.0±0.0 °C at 760 mmHg

[ Melting Point ]:
−23-−22 °C(lit.)

[ Molecular Formula ]:
C₇H₃BrClF₃

[ Molecular Weight ]:
259.451

[ Flash Point ]:
94.4±0.0 °C

[ Exact Mass ]:
257.905853

[ LogP ]:
3.83

[ Vapour Pressure ]:
0.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.492

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39-S36/39-S45-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Precursor & DownStream

Precursor

DownStream

1-Chloro-2-fluoro-4-(trifluoromethyl)benzene
2-Chloro-5-(trifluoromethyl)benzoyl chloride
2-Chloro-5-(trifluoromethyl)benzoic acid
2-Chloro-5-(trifluoromethyl)phenylboronic acid pinacol ester
2-bromo-1-phenoxy-4-(trifluoromethyl)benzene
3-(trifluoromethyl)-10H-phenothiazine

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Preparation of functionalized organomanganese(II) reagents by direct insertion of manganese to aromatic and benzylic halides.

Org. Lett. 13(12) , 3198-201, (2011)

Functionalized arylmanganese compounds were prepared using commercial manganese powder in the presence of LiCl and catalytic amounts of both 2.5% InCl(3) and 2.5% PbCl(2) (THF, 0-50 °C). In addition, ...