3-Bromo-4-chlorobenzotrifluoride

3-Bromo-4-chlorobenzotrifluoride Structure
3-Bromo-4-chlorobenzotrifluoride structure
Common Name 3-Bromo-4-chlorobenzotrifluoride
CAS Number 454-78-4 Molecular Weight 259.451
Density 1.7±0.1 g/cm3 Boiling Point 189.0±0.0 °C at 760 mmHg
Molecular Formula C7H3BrClF3 Melting Point −23-−22 °C(lit.)
MSDS USA Flash Point 94.4±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

Preparation of functionalized organomanganese(II) reagents by direct insertion of manganese to aromatic and benzylic halides.

Org. Lett. 13(12) , 3198-201, (2011)

Functionalized arylmanganese compounds were prepared using commercial manganese powder in the presence of LiCl and catalytic amounts of both 2.5% InCl(3) and 2.5% PbCl(2) (THF, 0-50 °C). In addition, benzylic manganese reagents are obtained at 25 °C in ca. 70...