tetryl

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Names

[ CAS No. ]:
479-45-8

[ Name ]:
tetryl

[Synonym ]:
N-METHYL-N,2,4,6-TETRANITROANILINE
Nitramine
2,4,6-trinitrophenylmethylnitramine
EINECS 207-531-9
2,4,6-trinitrophenyl-N-methylnitramine
N-methyl-N-(2,4,6-trinitrophenyl)nitramide
2,4,6-Tetryl
N-Methyl-N-picrylnitramine
Picrylmethylnitramine
Tetril
Tetralite
N-Picryl-N-methylnitramine
Picrylnitromethylamine
Tetryl
N-2,4,6-tetranitro-N-methylaniline

Chemical & Physical Properties

[ Density]:
1.803g/cm3

[ Boiling Point ]:
503.7ºC at 760mmHg

[ Melting Point ]:
130ºC

[ Molecular Formula ]:
C₇H₅N₅O₈

[ Molecular Weight ]:
287.14300

[ Flash Point ]:
258.4ºC

[ Exact Mass ]:
287.01400

[ PSA ]:
186.52000

[ LogP ]:
3.13190

[ Index of Refraction ]:
1.686

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BY6300000

CHEMICAL NAME :: Aniline, N-methyl-N,2,4,6-tetranitro-

CAS REGISTRY NUMBER :: 479-45-8

BEILSTEIN REFERENCE NO. :: 0964788

LAST UPDATED :: 199712

DATA ITEMS CITED :: 31

MOLECULAR FORMULA :: C7-H5-N5-O8

MOLECULAR WEIGHT :: 287.17

WISWESSER LINE NOTATION :: WNN1&R BNW DNW ENW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Liver - fatty liver degeneration Kidney, Ureter, Bladder - changes in both tubules and glomeruli Kidney, Ureter, Bladder - interstitial nephritis

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5580 mg/kg/90D-C

TOXIC EFFECTS :: Blood - other changes Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain

MUTATION DATA

TYPE OF TEST :: Gene conversion and mitotic recombination

TEST SYSTEM :: Yeast - Saccharomyces cerevisiae

REFERENCE :: TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 5,11,1980 *** REVIEWS *** ACGIH TLV-TWA 1.5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1.5 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,255,1971 OSHA PEL (Gen Indu):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1.5 mg/m3 JAN 1993 OEL-BELGIUM:TWA 1.5 mg/m3 JAN 1993 OEL-DENMARK:TWA 1.5 mg/m3;Skin JAN 1993 OEL-FINLAND:TWA 1.5 mg/m3;STEL 3 mg/m3;Skin JAN 1993 OEL-FRANCE:TWA 1.5 mg/m3;Skin JAN 1993 OEL-GERMANY:TWA 1.5 mg/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 15 mg/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 1.5 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 1.5 mg/m3;Skin JAN 1993 OEL-TURKEY:TWA 1.5 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1.5 mg/m3;STEL 3 mg/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TETRYL-air:10H TWA 1.5 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302 + H312 + H332-H319

[ Precautionary Statements ]:
P210-P261-P302 + P352 + P312-P304 + P340 + P312-P337 + P313-P403 + P235

[ Hazard Codes ]:
E,T,F

[ Risk Phrases ]:
2-23/24/25-33-36/37/38-11

[ Safety Phrases ]:
35-45-27-16

[ RIDADR ]:
0208

[ WGK Germany ]:
3

[ Hazard Class ]:
1.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-amino-2,6-dinitrotoluene
Sulfuric acid
2,4-Dinitro-N-methylaniline
N,N-Dimethylaniline
Benzenamine,N-methyl-2-nitro-
N-Methylaniline
n-nitroso-n-methylaniline
Benzenamine,N-methyl-4-nitroso-
N-methyl-4-carboxy-2,6-dinitroaniline
N-methyl-N-(2-nitrophenyl)nitramide

DownStream

Trinitrophenol
methylamine
Benzenamine,2,4,6-trinitro-
nitric acid
nitrous acid
Benzenamine,N-methyl-2,4,6-trinitro-
N-methyl-2,4,6-trinitro-N-nitroso-aniline
Benzenamine,N-(3-methylphenyl)-2,4,6-trinitro-
Benzenamine,N-(4-methylphenyl)-2,4,6-trinitro-
N-(4-methoxy-2,6-dinitrophenyl)-N-methylnitramide

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