(S)-1-(tert-Butoxycarbonyl)-2,5-dihydro-1H-pyrrole-2-carboxylic acid

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Names

[ CAS No. ]:
51154-06-4

[ Name ]:
(S)-1-(tert-Butoxycarbonyl)-2,5-dihydro-1H-pyrrole-2-carboxylic acid

[Synonym ]:
N-tert-Butoxycarbonyl-(S)-dehydroproline
(2S)-1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-2,5-dihydro-1H-pyrrole-2-carboxylic acid
(2S)-1-(tert-butoxycarbonyl)-2,5-dihydro-1H-pyrrole-2-carboxylic acid
(S)-1-Boc-2,5-dihydro-1H-pyrrole-2-carboxylic acid
Boc-3,4-Dehydro-L-proline
MFCD00037896
Boc-3,4-Dehydro-Pro-OH
1H-Pyrrole-1,2-dicarboxylic acid, 2,5-dihydro-, 1-(1,1-dimethylethyl) ester, (2S)-
(S)-2,5-dihydropyrrole-1,2-dicarboxylic acid 1-tert-butyl ester
AmbotzBAA1460

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
336.4±42.0 °C at 760 mmHg

[ Melting Point ]:
92-95ºC

[ Molecular Formula ]:
C10H15NO4

[ Molecular Weight ]:
213.230

[ Flash Point ]:
157.3±27.9 °C

[ Exact Mass ]:
213.100113

[ PSA ]:
66.84000

[ LogP ]:
0.53

[ Vapour Pressure ]:
0.0±1.6 mmHg at 25°C

[ Index of Refraction ]:
1.521

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319-H400

[ Precautionary Statements ]:
P273-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi,N

[ Risk Phrases ]:
R36

[ Safety Phrases ]:
26-60-61

[ RIDADR ]:
UN 3077 9 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Di-tert-butyl dicarbonate
  • 3,4-Dehydro-L-proline
  • methyl n-boc-l-proline-3-ene
  • (2S,4R)-1-(TERT-BUTOXYCARBONYL)-4-((METHYLSULFONYL)OXY)PYRROLIDINE-2-CARBOXYLIC ACID
  • BOC-ON
  • tert-butyl n,n-diallylcarbamate
  • N-Boc-3-pyrroline
  • Methyl 1H-pyrrole-2-carboxylate
  • 2-Trichloroacetylpyrrole

DownStream

  • methyl n-boc-l-proline-3-ene

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Peptide analogues compete with the binding of alpha-factor to its receptor in Saccharomyces cerevisiae.

J. Biol. Chem. 263 , 17333-17341, (1988)

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