Tris(dibenylideneacetone)dipalladium-chloroform

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Names

[ CAS No. ]:
52522-40-4

[ Name ]:
Tris(dibenylideneacetone)dipalladium-chloroform

[Synonym ]:
1,2,4,5-Pentanetetrayl, 3-oxo-1,5-diphenyl-, compd. with trichloromethane, palladium salt (3:1:2)
Tris(dibenylideneacetone)dipalladium-chloroform
Pd2(dba)3.CHCl3
N,N,N',N',N'',N''-Hexaallyl-1,3,5-triazine-2,4,6-triamine
1,4-Pentadien-3-one, 1,5-diphenyl-, (1E,4E)-, compd. with trichloromethane, palladium salt (3:1:2)
Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Tris(dibenzylideneacetone)dipalladium(0)-chloroform Adduct
Dipalladium-tris(dibenzylideneacetone)chloroform complex
MFCD00075479
Tris(dibenzylideneacetone)dipalladium-chloroformadduct

Chemical & Physical Properties

[ Boiling Point ]:
400.7ºC at 760mmHg

[ Melting Point ]:
131-135ºC

[ Molecular Formula ]:
C52H43Cl3O3Pd2

[ Molecular Weight ]:
1035.095

[ Flash Point ]:
176.2ºC

[ Exact Mass ]:
1032.034790

[ PSA ]:
51.21000

[ LogP ]:
13.93330

[ Storage condition ]:
0-6°C

[ Water Solubility ]:
Soluble in organic solvents. Insoluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H351

[ Precautionary Statements ]:
P281

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Palladium
  • dibenzylideneacetone

DownStream

  • ALLYLTRIETHYLGERMANE
  • Tetrakis(triphenylphosphine)palladium
  • Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)

Articles

J. Org. Chem. 55 , 3388, (1990)

Tetrahedron Lett. 30 , 651, (1989)

Chemistry 12 , 5657, (2006)


More Articles

Related Compounds

  • Tris(dibenzylideneacetone)dipalladium(0)
  • Tris(dibenzylideneacetone)dipalladium
  • Tris(dibenzylidineacetone)-dipalladium(o)
  • tris(4-bromomethyl phenyl)boroxine
  • tris[(4-chlorophenyl)sulfanyl]arsane
  • tris[tri(2-hydroxyethyl)ammonium] orthoborate
  • 6-Chloro-2-methyl-3-(5-methyl-1,3,4-oxadiazol-2-yl)pyridine
  • 1-(6-Bromopyridin-2-yl)ethane-1,2-diol
  • 1-(6-Bromopyridin-2-yl)-2-fluoroethanol
  • 6-chloro-N-(cyclopropylmethyl)-2-methylpyridin-3-amine
  • 3-[(4-Bromopyrimidin-2-yl)methyl]-1,3-oxazolidin-2-one
  • N-(cyanomethyl)-2-[3,5-dimethyl-1-(2-methylpropyl)-1H-pyrazol-4-yl]-N-(3-fluorophenyl)acetamide
  • (1R,2R)-1-((tert-Butoxycarbonyl)amino)-2-ethylcyclopropane-1-carboxylic acid
  • 2-chloro-N-[2-(pyridin-2-yl)-1H-1,3-benzodiazol-5-yl]pyridine-3-carboxamide
  • 4-Methoxy-3-methyl-2-[(4-trifluoromethyl-thiazole-2-carbonyl)-amino]-benzoic acid methyl ester
  • 3-{[(5-Methyl-1,2-oxazol-3-yl)methyl](prop-2-yn-1-yl)amino}-1lambda6-thiolane-1,1-dione
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