Tris(dibenylideneacetone)dipalladium-chloroform

Tris(dibenylideneacetone)dipalladium-chloroform Structure
Tris(dibenylideneacetone)dipalladium-chloroform structure
Common Name Tris(dibenylideneacetone)dipalladium-chloroform
CAS Number 52522-40-4 Molecular Weight 1035.095
Density N/A Boiling Point 400.7ºC at 760mmHg
Molecular Formula C52H43Cl3O3Pd2 Melting Point 131-135ºC
MSDS Chinese USA Flash Point 176.2ºC
Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Warning

J. Org. Chem. 55 , 3388, (1990)

Tetrahedron Lett. 30 , 651, (1989)

Chemistry 12 , 5657, (2006)

Palladium (II)-catalyzed tandem cyclic carbopalladation-vinylation of enyne compounds. Yamada H, et al.

Tetrahedron Lett. 38(17) , 3027-30, (1997)

Palladate salts from ionic liquids as catalysts in the Heck reaction. Gayet M,et al.

ARKIVOC 17 , 61-76, (2008)

Asymmetric synthesis of new beta,beta-difluorinated cyclic quaternary alpha-amino acid derivatives.

Org. Lett. 8 , 4129, (2006)

The synthesis of new beta,beta-difluorinated cyclic quaternary alpha-amino acid derivatives 1 in which a ring-closing metathesis reaction (RCM) constitutes the key step is described. The approach employs imidoyl chlorides 3 as fluorinated building blocks, and...

An efficient, palladium-catalyzed, enantioselective synthesis of (2R)-3-butene-1,2-diol and its use in highly selective Heck reactions.

Proc. Natl. Acad. Sci. U. S. A. 101(15) , 5396-9, (2004)

A robust and scalable procedure for the palladium-catalyzed dynamic kinetic asymmetric transformation of 3,4-epoxy-1-butene into (2R)-3-butene-1,2-diol with water as the cosolvent is reported. Examination of the effects of solvent and temperature led to the i...