1-Benzyl-3-pyrrolidinone

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Names

[ Name ]:
1-Benzyl-3-pyrrolidinone

[Synonym ]:
1-benzylpyrrolidin-2-one
1-Benzyl-3-pyrrolidinone
N-benzyl-3-pyrrolidinone
MFCD00003195
1-benzylpyrrolidin-3-one
2-Pyrrolidinone, 1-(phenylmethyl)-
3-Pyrrolidinone, 1-(phenylmethyl)-
1-Benzyl-2-pyrrolidinone
N-Benzylpyrrolidin-2-one
EINECS 226-131-5

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
343.0±21.0 °C at 760 mmHg

[ Melting Point ]:
154 - 156ºC

[ Molecular Formula ]:
C₁₁H₁₃NO

[ Molecular Weight ]:
175.227

[ Flash Point ]:
141.3±12.6 °C

[ Exact Mass ]:
175.099716

[ PSA ]:
20.31000

[ LogP ]:
1.25

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.578

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933790090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Pyrrolidinone
Benzaldehyde
gamma-Butyrolactone
Benzylamine
N-Allylbenzylamine
carbon monoxide
(E)-N-allyl-N-benzyl-3-chloroprop-2-en-1-amine
(E)-N-benzyl-3-chloro-N-((E)-3-chloroallyl)prop-2-en-1-amine
4-(benzylamino)butanoic acid

DownStream

1,2-Dimethoxybenzene
1-benzyl-3-(3,4-dimethoxyphenyl)-2-pyrrolidinone
1-benzyl-2,2-dimethylpyrrolidine
2-Pyrrolidinone
4-(benzylamino)butanoic acid
N-Phenylmethyl succinimide
1-Benzoylpyrrolidin-2-one
(S)-1-BENZYL-4-HYDROXYPYRROLIDIN-2-ONE
1-Benzyl-2-oxo-3-pyrrolidinecarboxylic acid
1-benzylpyrrolidine

Customs

[ HS Code ]: 2933790090

[ Summary ]:
2933790090. other lactams. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:9.0%. General tariff:20.0%

Articles

Aminoborohydrides. 11. Facile reduction of N-alkyl lactams to the corresponding amines using lithium aminoborohydrides.

Org. Lett. 1(5) , 799-801, (1999)

[reaction: see text] Various five- and six-membered N-alkyl lactams were reduced to the corresponding cyclic amines using lithium N,N-dialkylaminoborohydrides (LAB). Most of the reductions were essent...

1-Benzyl-3-pyrrolidinone
1-Benzyl-3-pyrrolidinone HCl
1-benzyl-3-(3,4-dimethoxyphenyl)-2-pyrrolidinone
1-benzyl-3-chloropyrrolidin-2-one
1-benzyl-3-chloro-4-(chloromethyl)pyrrolidin-2-one
1-benzyl-3-methylpiperidin-2-one
1-[(2S)-4-(benzyloxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-oxobutanoyl]-3-methylpiperidine-3-carboxylic acid
(2S)-2-({1-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopropyl}formamido)-4-methoxy-4-oxobutanoic acid
4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-[(4-methoxy-4-oxobutan-2-yl)carbamoyl]butanoic acid
2-[2-(ethyl carboxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)acetamido]-3-methoxy-2-methylpropanoic acid
2-{4-[(2S)-3-(benzyl carboxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]-1H-pyrazol-1-yl}acetic acid
3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-[4-(methoxycarbonyl)piperidin-1-yl]-4-oxobutanoic acid
2-[(2S)-3-(benzyl carboxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]-2-(methoxymethyl)butanoic acid
2-{1-[(2S)-3-(benzyl carboxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]cyclopropyl}acetic acid
3-[(2S)-3-(benzyl carboxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]-3-cyclobutylpropanoic acid
2-[(2S)-1-[(2S)-4-(benzyloxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-oxobutanoyl]piperidin-2-yl]acetic acid

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