a-Oxobenzeneacetaldehyde Aldoxime

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Names

[ CAS No. ]:
532-54-7

[ Name ]:
a-Oxobenzeneacetaldehyde Aldoxime

[Synonym ]:
(2E)-2-(Hydroxyimino)-1-phenylethanone
Benzeneacetaldehyde, α-oxo-, aldoxime
EINECS 208-539-5
2-Oxo-2-phenylacetaldehyde oxime
2-Hydroxyiminoacetophenone
ω-(Hydroxyimino)acetophenone
Isonitrosoacetophenone
(2E)-2-hydroxyimino-1-phenylethanone
Phenylglyoxaldoxim
a-Oxobenzeneacetaldehyde Aldoxime
Benzoylformaldoxime
ω-Isonitrosoacetophenone
Benzeneacetaldehyde, α-oxo-, α-oxime
MFCD00002122

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
305.7±25.0 °C at 760 mmHg

[ Melting Point ]:
123-125 °C

[ Molecular Formula ]:
C8H7NO2

[ Molecular Weight ]:
149.147

[ Flash Point ]:
138.7±23.2 °C

[ Exact Mass ]:
149.047684

[ PSA ]:
49.66000

[ LogP ]:
1.41

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.543

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
SOLUBLE IN COLD WATER

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MD3325000
CHEMICAL NAME :
Glyoxal, 1-phenyl-, 2-oxime
CAS REGISTRY NUMBER :
532-54-7
BEILSTEIN REFERENCE NO. :
2041691
LAST UPDATED :
199709
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C8-H7-N-O2
MOLECULAR WEIGHT :
149.16
WISWESSER LINE NOTATION :
QNU1VR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,27,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Behavioral - coma
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 119,522,1957

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S36/37-S24/25

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ RTECS ]:
MD3325000

[ HS Code ]:
2928000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Phenylglyoxal
  • Acetophenone
  • 1-phenyl(trimethylsiloxy)ethylene
  • 2,2-Dihydroxy-1-phenylethan-1-one
  • Glycolophenone
  • Isopropyl nitrite
  • Ethyl 3-oxo-3-phenylpropanoate
  • Benzenepropanoic acid, β-oxo-, methyl ester
  • N-Methyl-N-nitroso-trans-styrylamin
  • Benzaldehyde

DownStream

  • Phenyl ethyl ketone
  • Pyrazine, 2,5-diphenyl-
  • Benzamide
  • Urea
  • 2,2-Diphenylethanamine
  • Phenylglyoxylic acid
  • benzoic acid
  • Dibenzoylfuroxane
  • 4-PHENYLISOXAZOLE
  • (R)-1-Phenyl-1,2-ethanediol

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Biotransformation of isonitrosoacetophenone (2-keto-2-phenyl-acetaldoxime) in tobacco cell suspensions.

Biotechnol. Lett. 34(7) , 1351-6, (2012)

Nicotiana tabacum cell suspensions, 2 g wet wt/ml, rapidly took up 1 mM isonitrosoacetophenone (INAP), a plant-derived stress metabolite with anti-oxidative and anti-fungal properties, producing 4'-he...

Neuropathy target esterase: rates of turnover in vivo following covalent inhibition with phenyl di-n-pentylphosphinate.

J. Neurochem. 51(4) , 1097-101, (1988)

Phenyl di-n-pentylphosphinate is a reasonably stable easily synthesized inhibitor of neuropathy target esterase (NTE) with low anticholinesterase activity. Like phenylmethylsulphonyl fluoride it prote...

Synthesis and evaluation of 4-(3-methyl-2-butenoxy) isonitrosoacetophenone, a radiation-induced stress metabolite in Citrus.

Phytochemistry 50(6) , 983-9, (1999)

The time- and dose-dependent occurrence of 4-(3-methyl-2-butenoxy)isonitrosoacetophenone, a gamma-irradiation-induced stress metabolite was investigated. The chemical synthesis of the compound is repo...


More Articles

Related Compounds

  • 2,3-dichloro-α-oxobenzeneacetaldehyde aldoxime
  • a 02056
  • a-D-Ribofuranoside, methyl2,3-anhydro-, 4-nitrobenzoate (9CI)
  • A-(4-FLUOROPHENYL)-G-PHENYLACETOACETONITRILE
  • a-D-gluco-Hexodialdo-1,5-pyranoside,methyl
  • A-Nor-stachan-2-ol
  • 1-((5-((4-chlorobenzyl)thio)-1,3,4-oxadiazol-2-yl)methyl)pyrimidine-2,4(1H,3H)-dione
  • methyl 4-(((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)methyl)benzoate
  • methyl 5-(((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)methyl)furan-2-carboxylate
  • 1-((5-((3,3-dimethyl-2-oxobutyl)thio)-1,3,4-oxadiazol-2-yl)methyl)pyrimidine-2,4(1H,3H)-dione
  • N-(3-(2-((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)acetyl)phenyl)acetamide
  • 2-((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)acetamide
  • N-cyclopropyl-2-((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)acetamide
  • 2-((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)-N-(furan-2-ylmethyl)acetamide
  • N-(2-chloro-6-fluorobenzyl)-2-((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)-N-methylacetamide
  • 2-((5-((2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)methyl)-1,3,4-oxadiazol-2-yl)thio)-N-(4-fluorobenzyl)acetamide
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