a-Oxobenzeneacetaldehyde Aldoxime

Modify Date: 2024-01-10 21:01:57

a-Oxobenzeneacetaldehyde Aldoxime Structure
a-Oxobenzeneacetaldehyde Aldoxime structure
Common Name a-Oxobenzeneacetaldehyde Aldoxime
CAS Number 532-54-7 Molecular Weight 149.147
Density 1.1±0.1 g/cm3 Boiling Point 305.7±25.0 °C at 760 mmHg
Molecular Formula C8H7NO2 Melting Point 123-125 °C
MSDS Chinese USA Flash Point 138.7±23.2 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2-Isonitrosoacetophenone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 305.7±25.0 °C at 760 mmHg
Melting Point 123-125 °C
Molecular Formula C8H7NO2
Molecular Weight 149.147
Flash Point 138.7±23.2 °C
Exact Mass 149.047684
PSA 49.66000
LogP 1.41
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.543
Storage condition 2-8°C
Water Solubility SOLUBLE IN COLD WATER

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MD3325000
CHEMICAL NAME :
Glyoxal, 1-phenyl-, 2-oxime
CAS REGISTRY NUMBER :
532-54-7
BEILSTEIN REFERENCE NO. :
2041691
LAST UPDATED :
199709
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C8-H7-N-O2
MOLECULAR WEIGHT :
149.16
WISWESSER LINE NOTATION :
QNU1VR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,27,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Behavioral - coma
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 119,522,1957

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H312-H332
Precautionary Statements P280
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S36/37-S24/25
RIDADR 2811
WGK Germany 3
RTECS MD3325000
HS Code 2928000090

 Synthetic Route

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Articles3

More Articles
Biotransformation of isonitrosoacetophenone (2-keto-2-phenyl-acetaldoxime) in tobacco cell suspensions.

Biotechnol. Lett. 34(7) , 1351-6, (2012)

Nicotiana tabacum cell suspensions, 2 g wet wt/ml, rapidly took up 1 mM isonitrosoacetophenone (INAP), a plant-derived stress metabolite with anti-oxidative and anti-fungal properties, producing 4'-he...

Neuropathy target esterase: rates of turnover in vivo following covalent inhibition with phenyl di-n-pentylphosphinate.

J. Neurochem. 51(4) , 1097-101, (1988)

Phenyl di-n-pentylphosphinate is a reasonably stable easily synthesized inhibitor of neuropathy target esterase (NTE) with low anticholinesterase activity. Like phenylmethylsulphonyl fluoride it prote...

Synthesis and evaluation of 4-(3-methyl-2-butenoxy) isonitrosoacetophenone, a radiation-induced stress metabolite in Citrus.

Phytochemistry 50(6) , 983-9, (1999)

The time- and dose-dependent occurrence of 4-(3-methyl-2-butenoxy)isonitrosoacetophenone, a gamma-irradiation-induced stress metabolite was investigated. The chemical synthesis of the compound is repo...

 Synonyms

(2E)-2-(Hydroxyimino)-1-phenylethanone
Benzeneacetaldehyde, α-oxo-, aldoxime
EINECS 208-539-5
2-Oxo-2-phenylacetaldehyde oxime
2-Hydroxyiminoacetophenone
ω-(Hydroxyimino)acetophenone
Isonitrosoacetophenone
(2E)-2-hydroxyimino-1-phenylethanone
Phenylglyoxaldoxim
a-Oxobenzeneacetaldehyde Aldoxime
Benzoylformaldoxime
ω-Isonitrosoacetophenone
Benzeneacetaldehyde, α-oxo-, α-oxime
MFCD00002122