tris(methylthio)methane

Names

[ Name ]:
tris(methylthio)methane

[Synonym ]:
Methyl orthotrithioformate
Trithiomethoxymethane
Trimethyl trithioorthoformate
Orthoformic acid,trithio-,trimethyl ester
MFCD00009851

Chemical & Physical Properties

[ Density]:
1.16 g/mL at 25ºC(lit.)

[ Boiling Point ]:
102ºC15 mm Hg(lit.)

[ Melting Point ]:
16ºC(lit.)

[ Molecular Formula ]:
C₄H₁₀S₃

[ Molecular Weight ]:
154.31700

[ Flash Point ]:
204 °F

[ Exact Mass ]:
153.99400

[ PSA ]:
75.90000

[ LogP ]:
2.35900

[ Index of Refraction ]:
n20/D 1.577(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 2810 6

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Catalytic enantioselective synthesis of naturally occurring butenolides via hetero-allylic alkylation and ring closing metathesis.

Org. Lett. 13(5) , 948-51, (2011)

An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synth...

Research on L-nucleosides. Synthesis and biological evaluation of a series of L- and D-2',3'-dideoxy-3'-[tris(methylthio)methyl]-beta-pentofuranosyl nucleosides.

Bioorg. Med. Chem. 11(3) , 357-66, (2003)

Novel nucleoside analogues of both D and L enantiomeric series were prepared by coupling reaction between a 2',3'-dideoxy-3'-modified furanose moiety and four different nucleobases. Though in all case...

From ketones, aldehydes or alkyl halides to terminal 1, 1-difluoroolefins using BrF₃. Hagooly A and Rozen S.

J. Fluor. Chem. 126(8) , 1239-45, (2005)

Tris(methylthio)phosphine
tris(methylthio)methyl lithium
(Methylsulfinyl)(methylthio)methane
Tetrakis(methylthio)methane
(METHYLSULFONYL)(METHYLTHIO)METHANE
tris-methylsulfanyl-methane sulfuric acid monomethyl ester salt
(2E)-1-[5-{[2-(4-chlorophenyl)-2-oxoethyl]sulfanyl}-3-(4-methoxyphenyl)-1H-1,2,4-triazol-1-yl]-3-(4-methoxyphenyl)prop-2-en-1-one
4-chloro-N-(1,1-dioxidotetrahydrothiophen-3-yl)-3-(piperidin-1-ylsulfonyl)benzamide
(4-Chloro-3-(morpholinosulfonyl)phenyl)(4-(3-chlorophenyl)piperazin-1-yl)methanone
(4-(Benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)(4-chloro-3-(morpholinosulfonyl)phenyl)methanone
Ethyl 2-((5-(4-chloro-3-(piperidin-1-ylsulfonyl)benzamido)-1,3,4-thiadiazol-2-yl)thio)acetate
4-chloro-N-(3-((difluoromethyl)sulfonyl)phenyl)-3-(piperidin-1-ylsulfonyl)benzamide
4-Chloro-3-(morpholine-4-sulfonyl)-N-{5-[(2-oxo-2-phenylethyl)sulfanyl]-1,3,4-thiadiazol-2-YL}benzamide
2-(3-((5-(2,3-dihydrobenzo[b][1,4]dioxin-2-yl)-4-phenyl-4H-1,2,4-triazol-3-yl)thio)propyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione
(E)-2-(3-(azepan-1-ylsulfonyl)-4-methoxystyryl)benzo[d]thiazole
4-chloro-N-(5-((2-oxo-2-phenylethyl)thio)-1,3,4-thiadiazol-2-yl)-3-(piperidin-1-ylsulfonyl)benzamide

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