tris(methylthio)methane

tris(methylthio)methane Structure
tris(methylthio)methane structure
Common Name tris(methylthio)methane
CAS Number 5418-86-0 Molecular Weight 154.31700
Density 1.16 g/mL at 25ºC(lit.) Boiling Point 102ºC15 mm Hg(lit.)
Molecular Formula C4H10S3 Melting Point 16ºC(lit.)
MSDS Chinese USA Flash Point 204 °F
Symbol GHS07
GHS07
Signal Word Warning

Catalytic enantioselective synthesis of naturally occurring butenolides via hetero-allylic alkylation and ring closing metathesis.

Org. Lett. 13(5) , 948-51, (2011)

An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated wi...

Research on L-nucleosides. Synthesis and biological evaluation of a series of L- and D-2',3'-dideoxy-3'-[tris(methylthio)methyl]-beta-pentofuranosyl nucleosides.

Bioorg. Med. Chem. 11(3) , 357-66, (2003)

Novel nucleoside analogues of both D and L enantiomeric series were prepared by coupling reaction between a 2',3'-dideoxy-3'-modified furanose moiety and four different nucleobases. Though in all cases anomeric mixtures of nucleosides were obtained, the prese...

From ketones, aldehydes or alkyl halides to terminal 1, 1-difluoroolefins using BrF3. Hagooly A and Rozen S.

J. Fluor. Chem. 126(8) , 1239-45, (2005)