Benzyl bromoacetate

Suppliers

Names

[ Name ]:
Benzyl bromoacetate

[Synonym ]:
benzyl 2-bromo-acetate
Bromoacetic acid benzyl ester
phenylmethyl 2-bromoacetate
Merbac 35
EINECS 226-611-4
Acetic acid,bromo-,benzyl ester
phenylmethyl bromoacetate
Benzyl bromoacetate
Acetic acid,bromo-,phenylmethyl ester
2-Bromoacetic Acid Phenylmethyl Ester
MFCD00000190
Acetic acid, 2-bromo-, phenylmethyl ester
Caswell No. 082A
bromoacetic acid. phenylmethyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
287.8±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₉BrO₂

[ Molecular Weight ]:
229.071

[ Flash Point ]:
116.5±20.4 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
2.66

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.556

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AF5957215

CHEMICAL NAME :: Acetic acid, bromo-, benzyl ester

CAS REGISTRY NUMBER :: 5437-45-6

BEILSTEIN REFERENCE NO. :: 0973658

LAST UPDATED :: 199712

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C9-H9-Br-O2

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ RTECS ]:
AF5957215

[ Hazard Class ]:
6.1

[ HS Code ]:
29159080

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Bromoacetic acid
Benzyl alcohol
Bromoacetyl bromide
Methyl bromoacetate
1-acetoxy-2-nitroethane
5-AMINO-3-AMINOSULFONY-4-PHENOXYBENZOICACID
ethyl 2-bromoacetate
1-ETHOXYCYCLOPROPANOL
Dibenzyl ether

DownStream

Benzyl acetylacetate
Benzyl (dimethoxyphosphoryl)acetate
Dimethyl methylphosphonate
benzyl 2-(2-oxopyrrolidin-1-yl)acetate
Benzyl acetate
(4,7,10-TRIS-BENZYLOXYCARBONYLMETHYL-1,4,7,10TETRAAZA-CYCLODODEC-1-YL)-ACETIC ACID
BENZYL 2-(BENZYLOXY)ACETATE
10-(2-BENZOTHIAZOLYL)-2,3,6,7-TETRAHYDRO-1,1,7,7-TETRAMETHYL-1H,5H,11H-(1)BENZOPYROPYRANO(6,7-8-I,J)QUINOLIZIN-11-ONE
hydroxyl(4-phenylbutyl)pjosphinyl]benzyl acetate
Benzyl cinnamate

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of VIP-lipopeptide using a new linker to modify liposomes: towards the development of a drug delivery system for active targeting.

Chem. Pharm. Bull. 61(11) , 1184-7, (2013)

A new component for the solid phase peptide synthesis of lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid (2), was designed...

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benzyl-phthalimido-malonic acid diethyl ester
Benzyl 3-[L-alanyl(isopropyl)amino]-1-pyrrolidinecarboxylate
(1S)-2-amino-1-(3,5-difluorophenyl)ethan-1-ol
(1R)-2-amino-1-[3,5-bis(trifluoromethyl)phenyl]ethan-1-ol
3-Cycloheptyl-2-methylpropan-1-ol
4-(3,4-Difluorophenyl)-2-methylbutan-1-ol
2-Bromo-1-(2,5-dimethoxyphenyl)ethan-1-ol
2-Bromo-1-(5-chlorothiophen-2-yl)ethan-1-ol
2-bromo-1-(1-ethyl-1H-pyrazol-4-yl)ethan-1-ol
2-Chloro-1-(2,6-difluorophenyl)ethan-1-ol
(1R)-1-(3-bromophenyl)-2-chloroethan-1-ol
(1S)-2-Amino-1-(2-chloro-4-fluorophenyl)ethan-1-ol

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